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Last update: Pátková Vlasta (19.11.2018)
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Last update: Pátková Vlasta (19.11.2018)
Students will be able to: • recognise the noncovalent interactions acting in a specific system • use the knowledge of noncovalent interactions for design of receptor suitable for the complexation of cations and/or anions) • design the 3D structure/shape of receptor for the complexation of neutral molecule • choose analytical methods suitable for the study of a given complex • suggest methods for the evaluation of the stability constants and thermodynamic parameters of the host-guest interaction • apply the principals of "self-assembly" for the synthesis of topological isomers • use the concepts of supramolecular chemistry in the advanced organic synthesis |
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Last update: Pátková Vlasta (19.11.2018)
(R) J. W. Steed, J. L. Atwood: Supramolecular Chemistry, 2nd Edition, Wiley 2009. ISBN 9780470512340 (A) J. W. Steed, J. L. Atwood (Eds.): Encyclopedia of Supramolecular Chemistry, 2004, CRC Press, ISBN 9780824750565 (A) Beer P. D., Gale P. A., Smith D. K.: Supramolecular Chemistry, Oxford Chemistry Primers, Oxford University Press 1999. 0198504470 + https://onlinelibrary.wiley.com/results/global-subject-codes/ch85?target=topic-title-results (Wiley Online Library available from VSCHT (UCT) intranet, more than 50 books focused on supramolecular chemistry) |
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Last update: Pátková Vlasta (19.11.2018)
http://intranet.vscht.cz/suprachemie (available at VSCHT (UCT) intranet, definition of basic terms, lectures in pdf format) https://onlinelibrary.wiley.com/results/global-subject-codes/ch85?target=topic-title-results (Wiley Online Library available at VSCHT (UCT) intranet, more than 50 books focused on supramolecular chemistry) |
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Last update: Pátková Vlasta (19.11.2018)
• What is supramolecular chemistry? Basic definitions and concepts. • Complexation of cations, anions and neutral compounds, chiral recognition. • Noncovalent interactions and their applications. • Structure determination, stability constant assignment and the evaluation of thermodynamic parameters of the corresponding supramolecular phenomenon (host-guest chemistry). • Overview of the most frequently used families of macrocyclic compounds. • Modular approach - the coordination chemistry of pyridines and bipyridines. • Biochemical applications of supramolecular chemistry • Pricipals of self-assembly and their applications. • Topological isomers (rotaxanes, catenanes, knotanes), nanomachines. • Liquid crystals. • Interfacial phenomena (micelles, Langmuir-Blodget, SAM) • Carbon allotropes (fullerenes, nanotubes, graphene). • Dendrimers and supramolecular chemistry of polymers. |
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Last update: Pátková Vlasta (19.11.2018)
PowerPoint presentation on selected topic (20%) Final test (40%) Oral examination (40%) |