SubjectsSubjects(version: 948)
Course, academic year 2023/2024
  
Inorganic and general chemistry B - N101027
Title: Obecná a anorganická chemie B
Guaranteed by: Department of Inorganic Chemistry (101)
Faculty: Faculty of Chemical Technology
Actual: from 2019
Semester: summer
Points: summer s.:6
E-Credits: summer s.:6
Examination process: summer s.:
Hours per week, examination: summer s.:2/2, C+Ex [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
Level:  
For type:  
Guarantor: Flemr Vratislav doc. Ing. CSc.
Sedmidubský David prof. Dr. Ing.
Class: Předměty pro matematiku
Is interchangeable with: N101006, AB101002, B101002
Examination dates   Schedule   
Annotation -
Last update: TAJ101 (03.12.2013)
The course extends the knowledge and skills acquired in the course OACH I. It covers the symmetry of polyatomic molecu, theory of molecular orbitals,chemical bonding in coordination complexes, concept of Lewis acids and bases, principles of solid state chemistry, chemical bonding in solids, phase and chemical equilibrium, basic electrochemistry and selected methods and synthesis techniques in the field of advanced and applied inorganic chemistry.
Aim of the course -
Last update: TAJ101 (03.12.2013)

Students will be able to:

Identify the symmetry elements and operations and to propose and apply the molecular orbital diagrams for polyatomic molecules

Determine the groud state terms of atoms and ions of d-block elements and their energy splitting in ligand field

Assess the acid-base behavior of ions in aqueous solutions and propose the reaction schemes for Lewis acids and bases

Characterize crystalline solids in terms of symmetry, derive the structure prototypes based on closed packing schemes of atoms and ions, and perform simple crystal chemical calculations (theoretical density, charge balances in non-stoichiometric solids)

Solve the problems involving various types of equilibrium constants, potential phase diagrams, standard reduction potentials and Nernst equations.

Apply an extended knowledge of inorganic substances reactivity.

Literature -
Last update: TAJ101 (02.09.2013)

R: C.E.Housecroft, A.G.Sharpe, Anorganická chemie, 4. vydání, VŠCHT Praha, 2014

R: J.Klikorka et al., Obecná a anorganická chemie, SNTL Praha, 1986, 0461285

A: G.Wulfsberg, Inorganic Chemistry, University Science Books, 2000, 98053513

A: D.Sýkorová et al., Návody pro laboratoře z anorganické chemie, VŠCHT Praha 1996, 8070802472

Learning resources -
Last update: TAJ101 (02.09.2013)

D.Sedmidubský et al.: Power Point presentations OACH-II - http://www.vscht.cz/ach/vyuka-bakalarske-oach-prednasky.html

Electronic supplementary materials - http://eso.vscht.cz/predmety/N101006/

Requirements to the exam -
Last update: TAJ101 (02.09.2013)

To obtain a credit the students have to successfully pass two preliminary tests during the semester or a summary test at the end of the semester. The examination covers the summary of the contents of both OACH I and OACH II and it constists of a written and oral part. Further information on the web site of the Department of inorganic chemistry (http://www.vscht.cz/ach/vyuka-bakalarske-oach2.html).

Syllabus -
Last update: TAJ101 (18.11.2012)

1. Electronic structure of atoms and ions with incomplete shells. Influence of electrostatic field.

2. Symmetry of molecules, group theory and its application in inorganic chemistry.

3. Chemical bonding in polyatomic molecules and complexes - molecular orbital theory.

4. Ions in aqueous solutions, acid-base properties, hydrolysis, solubility of salts.

5. Lewis theory of acids and bases and its implications in inorganic chemistry, LA-LB reaction mechanisms.

6. Complexes of transitions metals, structure, bonding, spectroscopic and magnetic properties

7. Complexes of transitions metals, coordination equilibria and reaction mechanisms.

8. Thermodynamic aspects of inorganic chemistry, thermochemistry and energetics, homogeneous a heterogeneous equlibrium, phase diagrams.

9. Principles of redox reactions, elektrochemistry fundamentals, Pourbaix diagrams.

10. Structure and symmetry of crystalline solids.

11. Crystal chemistry fundamentals. Basic structure types. Crystal defects.

12. Chemical bonding in solid substances and their properties.

13. Special inorganic technologies - deposition and processing of thin films, single crystal growth, sol-gel methods

14. Applied inorganic chemistry - industrially important inorganic chemicals

Entry requirements -
Last update: TAJ101 (18.09.2013)

For the enrollment a successful examination from General and Inorganic Chemistry I (N101005) is required.

Registration requirements -
Last update: TAJ101 (18.09.2013)

For the enrollment a successful examination from General and Inorganic Chemistry I (N101005) is required.

Teaching methods
Activity Credits Hours
Konzultace s vyučujícími 0.4 10
Účast na přednáškách 1 28
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1.1 30
Příprava na zkoušku a její absolvování 2.5 70
Účast na seminářích 1 28
6 / 6 166 / 168
Coursework assessment
Form Significance
Regular attendance 20
Examination test 30
Continuous assessment of study performance and course -credit tests 25
Oral examination 25

 
VŠCHT Praha