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This course extends the basic course Physical Chemistry I with focus on biological sciences. Covered are general laws governing behavior of systems from the molecular point of view as well as applications in biochemistry and colloidal chemistry. Poslední úprava: Kolafa Jiří (26.09.2013)
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Talks, exercises: http://old.vscht.cz/fch/en/tools/kolafa/S403016.html Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 Physical chemistry in brief: http://old.vscht.cz/fch/en/tools/breviary.html Poslední úprava: Kolafa Jiří (16.09.2015)
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Lectures, exercises. Poslední úprava: Kolafa Jiří (08.02.2018)
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1. Formal chemical kinetics: Concepts, simple and simultaneous reactions. 2. Reaction mechanisms, catalysis, enzyme kinetics (Michaelis–Menten), inhibition. 3. Equilibrium thermodynamics: Gibbs and Helmholtz functions, activity, chemical potential. Chemical equilibria, the direction of chemical reaction, simultaneous reactions. 4. Chemical equilibria in aqueuous solutions: pH, weak acids and bases and their salts, buffers, slightly soluble salts. 5. Statistical thermodynamics light: Pressure of ideal gas and the interpretation of temperature, Boltzmann probability, entropy. 6. Electrostatic phenomena in ionic solutions: Debye-Hückel theory, electrical double layer. 7. Electrochemistry: Galvanic cells, Nernst equation. 8. Thermodynamics of mixtures: Colligative properties, osmotic pressure. 9. Nonequilibrium thermodynamics: Transport properties, Fick's laws, diffusivity, electrical conductivity. 10. Interfaces: Surface and interface tension, wetting. Curved interfaces, nucleation. 11. Adsorption: Surface excess and Gibbs adsorption isotherm. Adsorption isotherms and models (Freundlich, Langmuir, BET). 12. Dispersion systems - classification: Colloid, sol, gel, foam, emulsion, aerosol; solutions of macromolecules; micelles, surface films. Rheology, optical properties. 13. Dispersion systems - phenomena: Forces between colloidal particles. Sedimentation, electrokinetic phenomena, zeta potential. 14. Stability of colloidal systems (DLVO theory). Poslední úprava: Kolafa Jiří (08.02.2018)
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Physicial Chemistry I or equivalent Mathematics I or equivalent Poslední úprava: Kolafa Jiří (26.09.2013)
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