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Course, academic year 2013/2014
  
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Inorganic thermodynamics and phase diagrams - D110029
Title: Anorganická termodynamika a fázové diagramy
Guaranteed by: Department of Inorganic Chemistry (101)
Faculty: Faculty of Chemical Technology
Actual: from 2013 to 2013
Semester: summer
Points: summer s.:0
E-Credits: summer s.:0
Examination process: summer s.:
Hours per week, examination: summer s.:0/0, other [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Qualifications:  
State of the course: taught
Language: Czech
Teaching methods: full-time
Level:  
Note: course is intended for doctoral students only
Guarantor: Holba Marek Ing. Ph.D.
Sedmidubský David prof. Dr. Ing.
Examination dates   Schedule   
Annotation -
The course is focused on the application of chemical thermodynamics to inorganic systems. It is devided into six blocks devoloping the fundamental thermodynamics concepts: Identity of inorganic substances, Heat and temperature, Models of inorganic phases, Conditions of thermodynamic equilibrium, Transitions and reactions, Phase diagrams of inorganic systems. The lectures are complemented by practical training focused on applications of calculation and database system FactSage for phase and chemical equilibria in inorgnaic substances.
Last update: Sedmidubský David (13.05.2014)
Course completion requirements -

A successful solution of a project related to the topic of thesis

Last update: VED101 (14.05.2014)
Literature -

R: H.A.J. Oonk, M.T. Calvet, Equilibrium Between Phase of Matter - Phenomenology and thermodynamics, Springer 2008, ISBN: 978-1-4020-6123-3

R: F. Weinhold, Classical and Geometrical Theory of Chemical and Phase Thermodynamics, John Wiley & Sons 2009, ISBN: 978-0-470-40236-8

A: H.L. Lucas, S.G.Fries, B.Sundman, Computational Thermodynamics - The Calphad Method, Cambridge University Press 2007, ISBN: 978-0-521-86811-2

Last update: Sedmidubský David (14.05.2014)
Syllabus -
  • Identity of substances, macroscopic and microscopic composition, chemical species and chemical phases
  • Heat and temperature, heat sources, heat capacity and latent heat, entropy and caloricum
  • Thermodynamic quantities and systems, predictors and predicants, thermodynamic axioms, Legendre transformations
  • Equations of state and thermodynamic models of phases
  • Phase relations and their representation - phase diagrams
  • Changes of matter - chemical reactions and phase transformations
Last update: Sedmidubský David (14.05.2014)
Learning outcomes -

Students will be able to:

analyze the inorganic systems based on mass balance matrices, determine the number of independent components and stoichiometry of independent reactions in a homogenneous system

construct thermodynamic models of inorganic phases

derive stoichiometric conditions of homogeneous equilibrium and solve the the equilibrium composition of a homogenneous system

derive stoichiometric conditions of phase equilibrium and construct simple phase diagrams

employ the nonstoichiometric algorithm based on constrained Gibbs energy minimim for equilibrium calculations of complex multicomponent systems

construct and interprete various types of phase diagrams

Last update: Sedmidubský David (14.05.2014)
Registration requirements -

Physical Chemistry II

Thermodynamics of Materials

Last update: VED101 (14.05.2014)
 
VŠCHT Praha