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The course deals with selected chapters of physical chemistry on advanced level. Knowledge acquired in the basic course Physical Chemistry I is extended to real-behaving systems. Subjects covered involve state behavior of matter, thermodynamics of fluids, phase and chemical equilibria, properties of electrolyte-containing systems, chemical kinetics, and basic concepts of surface chemistry.
Last update: Kubová Petra (06.03.2019)
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Acquiring credit (meeting the minimum requirements of the computational part) The exam (comutational test + oral exam) Last update: Řehák Karel (30.08.2024)
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R: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 R: Malijevský A., Physical Chemistry in Brief, Institute of Chemical-technology, 2005. PDF document will be available by the E-learning portal. Last update: Řehák Karel (14.08.2019)
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Combination of lectures and seminar meetings. Last update: Kubová Petra (06.03.2019)
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For participation in the exam each student has to get the credit from the seminar meetings. A student will be granted the credit when he/she gains the average 50 per cent of the maximum available from the written tests (partial tests during the semester or the summary test). Last update: Kubová Petra (06.03.2019)
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1. Molecular approach to physical chemistry. 2. Equations of state for real fluids, theorem of corresponding states. 3. Energetics of chemical reactions, enthalpy balance. 4. Implications of I. and II. Laws of thermodynamics, temperature and presseure dependences of state functions. 5. Thermodynamics of irreversible processes, heat engines, liquefacation of gases. 6. Thermodynamics of solutions, fugacity, activity. 7. Phase equilibia in real systems. 8. Spontaneous chemical change and Gibbs energy, chemical equilibrium in systems of various types. 9. Theory of electrolytic dissociation, equilibria in electrolyte solutions. 10.Difusion, migration of ions in electric field, conductivity, Kohlrausch law. 11.Reversible galvanic cells, types of electrodes, galvanic cells as power sources. 12.Kinetics of simultaneous reactions, kinetics and chemical equilibrium. 13.Reaction mechanisms; photochemical,radical, and catalyzed reactions. 14.Introduction to surface chemistry. Last update: Kubová Petra (06.03.2019)
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Basic information and learning resources: See E-learning
Other literature and learning applications: https://ufch.vscht.cz/studium/literatura https://ufch.vscht.cz/studium/elektronicke_pomucky Last update: Kubová Petra (06.03.2019)
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Students will be able to:
Last update: Kubová Petra (06.03.2019)
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Fyzikální chemie I, Matematika A, Matematika B, Fyzika I Last update: Kubová Petra (06.03.2019)
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Fyzikální chemie I, Matematika A, Matematika B Last update: Kubová Petra (06.03.2019)
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