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The subject focuses on the importance of transition metals for the composition and properties of molecules. It gives an overview of the approaches used to describe coordinating compounds, it deals with the properties of the metal and the ligand that are critical to the formation of complexes and what determines their properties (reactivity, interaction with IR and UV-Vis radiation, magnetic behavior, biological activity).
Last update: Hoskovcová Irena (21.02.2018)
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Each week a homework is given to the topic being discussed. In order to become eligible for classification each student has to work it out at least 7 times. The final exam is oral. Last update: Hoskovcová Irena (19.02.2018)
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J. Ribas Gispert: Coordination Chemistry, Wiley-VCH, 2008, ISBN: 978-3-527-31802-5 Y. Jean: Molecular Orbitals of Transition Metal Complexes, OxfordUP, 2005, ISBN: 0-19-853093-5 C. E. Housecroft, A. G. Sharpe:Inorganic Chemistry, 4th Ed., Pearson Edu. 2012, ISBN-13: 978-0273742753, ISBN-10: 0273742752 G. A. Lawrence: Introduction to Coordination Chemistry, Wiley 2010, ISBN: 978-0-470-51930-1, 978-0-470-51931-8 Last update: Hoskovcová Irena (20.02.2018)
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1. History of coordination chemistry 2. Crystal Field Theory, Ligand Field Theory. 3. Molecular orbitals in coordination compounds. 4. Coordination polyhedra, fluxionality. Continuous symmetry concept.. 5. Isomerism. Description ad determination of the absolute configuration. 6. Stability of coordination compounds, mechanisms of ligand substitution. 7. Ligands and their classification: nature of donor atoms, bonding possibilities. Chelates. 8. Metal - ligand interaction from the Lewis acid-base theory’s point of view. 9. Allyl complexes, metallocenes, cyclic ligands, template effect. 10. Polynuclear complexes, clusters. 11. Changes of ligand properties and reactivity after coordination to a metal centre. 12. Spectroscopy of coordination compounds. Photochemical reactions. 13. Magnetic properties of coordination compounds. Molecular magnets. 14. Electron transfer mechanisms. Last update: Kubová Petra (28.02.2018)
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e-learning: FCHT -> Ústav anorganické chemie -> Koordinační chemie At that place slides from lectures in English are available.
https://uach.vscht.cz/vyuka/magisterske-studium http://www.vscht.cz/ach/vyuka-magisterske-koordch.html Last update: Hoskovcová Irena (21.02.2018)
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Students will be able: to use basic terms of coordination chemistry to differentiate viewpionts of CFT, LFT and MO theories, to know their benefits and usability limits to explain the typical properties of coordinating compounds with help of a suitable model
They will be able to use the concepts necessary for the study of primary literature and monographs. Last update: Hoskovcová Irena (21.02.2018)
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| Teaching methods | ||||
| Activity | Credits | Hours | ||
| Konzultace s vyučujícími | 0.5 | 14 | ||
| Účast na přednáškách | 1.5 | 42 | ||
| Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
| Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
| Účast na seminářích | 1 | 28 | ||
| 6 / 6 | 168 / 168 | |||
| Coursework assessment | |
| Form | Significance |
| Regular attendance | 40 |
| Oral examination | 60 |