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In the first part of the course the students are familiarized with the fundamentals of electrochemistry as a specific approach to investigation of redox reactions at the electrode from thermodynamic, kinetic and mechanistic point of view. At that occasion important concepts, relationships and contexts will be clarified. In the second part the detailed overview of all main electrochemical techniques and electroanalytical methods will follow together with explanation of their principle and with description of their application possibilities in various areas of chemistry. Qualitative evaluation of the obtained data and the interpretation of results is also an important part of the course.
Last update: Bím Daniel (30.08.2026)
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The oral exam Last update: Bím Daniel (30.08.2026)
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R: Heyrovský J., Kůta J., Základy polarografie, Nakl. Československé akademie věd, Praha, 1962 R: Bard A.J., Faulkner L.R., Electrochemical Methods: Fundamentals and Applications, Wiley, 1980, 9780471055426 R: Koryta J., Dvořák J., Elektrochemie, Academia, Praha, 1983, A: Sawyer D.T, Sobkowiak A., Roberts J.L.: Electrochemistry for Chemists, Wiley 1995, 9780471594680 A: Wang, J.: Analytical Electrochemistry Wiley, 20069780471678793 A: Mindl, J.: Základy elektroorganické chemie, Academia, 2000. Last update: Bím Daniel (30.08.2026)
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1. Processes taking part on electrodes. 2. Electric double layer and its structure, adsorption, 3. Potentials and thermodynamics. 4. Mass transfer, microelectrodes, reversibility. 5. Kinetics of electrode reactions. 6. Potentiostatic methods (polarography, voltammetry, chronoamperometry) 7. Linear sweep potentiostatic methods (LSV, cyclic voltammetry). 8. Pulsing methods with analytical utilization (NPP, DPP). 9. Stripping analysis. 10.Galvanostatic methods. 11.Rotating electrodes. 12.AC - techniques and measurement of faradaic impedance. 13.Coulometry and preparative electrolysis. 14.Combination of electrochemistry with other methods (sono-, photo- and spectroelectrochemistry, electrochemiluminiscence). Last update: Bím Daniel (30.08.2026)
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Barek, J. a kol.: MOŽNOSTI INOVACÍ V ELEKTROANALYTICKÉ CHEMII, Praha 2006, http://www.vscht.cz/anl/paci/PAC/prezentace/elektroanalytika.pdf Last update: Bím Daniel (30.08.2026)
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Students will be able to:
gain knowledge of their possibilities and applications.
the instrumentation, to acquire experimental data and to make the first interpretation. Last update: Bím Daniel (30.08.2026)
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Physical chemistry I or General chemistry Last update: Bím Daniel (30.08.2026)
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| Teaching methods | ||||
| Activity | Credits | Hours | ||
| Konzultace s vyučujícími | 0.5 | 14 | ||
| Účast na přednáškách | 1 | 28 | ||
| Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 0.5 | 14 | ||
| Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
| Účast na seminářích | 0.5 | 14 | ||
| 4 / 4 | 112 / 112 | |||
| Coursework assessment | |
| Form | Significance |
| Regular attendance | 10 |
| Oral examination | 90 |
