Subjects

Your browser does not support JavaScript, or its support is disabled. Some features may not be available.

Coordination Chemistry - M101003

Title:	Koordinační chemie
Guaranteed by:	Department of Inorganic Chemistry (101)
Faculty:	Faculty of Chemical Technology
Actual:	from 2019 to 2022
Semester:	winter
Points:	winter s.:6
E-Credits:	winter s.:6
Examination process:	winter s.:
Hours per week, examination:	winter s.:3/1, C+Ex [HT]
Capacity:	unlimited / unlimited (unknown)
Min. number of students:	unlimited
State of the course:	taught
Language:	Czech
Teaching methods:	full-time
Teaching methods:	full-time
Level:
Note:	course can be enrolled in outside the study plan enabled for web enrollment

Guarantor:	Hoskovcová Irena Ing. CSc.
Interchangeability :	AM101003, N101011

Examination dates Schedule

This subject contains the following additional online materials

E-learning course

Annotation -

The course focuses on the importance of transition metals for the construction and properties of molecules. It provides an overview of the approaches used to describe coordination compounds, deals with what properties of the metal and ligand are crucial for the formation of complexes and what determines their properties (reactivity, interaction with IR and UV-Vis radiation, magnetic behavior, biological activity).

Last update: Pátková Vlasta (10.01.2018)

Aim of the course -

Students will be able to:

Use the basic coordination chemistry notions

Distinguish access CFT, LFT and MO theory, know their advantages and applicability limits

Explain the typical properties of coordination compounds using an appropriate model

Understand the primary literature and memoirs

Last update: Pátková Vlasta (10.01.2018)

Course completion requirements -

The subject is finished by the oral exam.

Last update: Nekvindová Pavla (16.02.2018)

Literature -

R: J. Ribas Gispert: Coordination Chemistry, Wiley-VCH, 2008, ISBN: 978-3-527-31802-5

A: Y. Jean: Molecular Orbitals of Transition Metal Complexes, OxfordUP, 2005, ISBN: 0-19-853093-5

A: R. Boča: Chémia koordinačných a organokovových zlúčenín, Nakladatelství STU, 2009, ISBN: 978-80-227-3082-2

A: příslušné kapitoly v učebnicích (Housecroft-Sharpe, Cotton-Wilkinson, Jolly, Wulfsberg, Greenwood-Earnshaw)

Last update: Hoskovcová Irena (15.02.2018)

Requirements to the exam -

Each week tasks related to actual topic is given. To obtain the credit the students should have to at least 7 times independently resolved this tasks. The exam is oral.

Last update: Pátková Vlasta (10.01.2018)

Syllabus -

1. History of coordination chemistry

2. Crystal Field Theory, Ligand Field Theory.

3. Molecular orbitals in coordination compounds.

4. Coordination polyhedra, fluxionality. Continuous symmetry concept..

5. Isomerism. Description ad determination of the absolute configuration.

6. Stability of coordination compounds, mechanisms of ligand substitution.

7. Ligands and their classification: nature of donor atoms, bonding possibilities. Chelates.

8. Metal � ligand interaction from the Lewis acid-base theory’s point of view.

9. Allyl complexes, metallocenes, cyclic ligands, template effect.

10. Polynuclear complexes, clusters.

11. Changes of ligand properties and reactivity after coordination to a metal centre.

12. Spectroscopy of coordination compounds. Photochemical reactions.

13. Magnetic properties of coordination compounds. Molecular magnets.

14. Electron transfer mechanisms.

Last update: Pátková Vlasta (10.01.2018)

Learning resources -

http://www.vscht.cz/ach/vyuka-magisterske-koordch.html

http://wwwchem.uwimona.edu.jm:1104/courses/Tanabe-Sugano/

Last update: Pátková Vlasta (10.01.2018)

Registration requirements -

General and Inorganic Chemistry II

Last update: Pátková Vlasta (10.01.2018)

Teaching methods
	Activity	Credits	Hours
	Konzultace s vyučujícími	0.5	14
	Účast na přednáškách	1.5	42
	Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi	1.5	42
	Příprava na zkoušku a její absolvování	1.5	42
	Účast na seminářích	1	28
		6 / 6	168 / 168