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The main aim of the course is to get knowledge of possible ways for calculation of equilibrium reaction mixtures and methods of its influence. Second part is dedicated to calculations of electrochemical systems, its operating parameters and efficiency. Beside theoretical background the main attention is paid to the calculations of real processes used in industry.
Last update: Paidar Martin (25.08.2015)
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Students will be able:
Last update: Paidar Martin (25.08.2015)
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R: M. Malinovský, I.Roušar a kol., Teoretické základy pochodů anorganické technologie, SNTL/ALFA, 1987 R: R. Mráz, J. Krýsa, Příklady z chemicko-inženýrské termodynamiky, skripta VŠCHT Praha, 1991 A: Atkins, P. W,De Paula, Julio, Fyzikální chemie, Vysoká škola chemicko-technologická, v Praze. 2013 Last update: ROZ105 (24.06.2015)
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1. Phase equilibrium in two component systems. 2. Phase equilibrium in three component systems. Graphical representation. 3. Cyclic crystallization between two temperatures. 4. Phase equilibrium in four component systems. Graphical representation. 5. Basic thermodynamic principles of systems with chemical reaction; reaction enthalpy, entropy, Gibbs energy 6. Calculation of the equilibrium conditions in gaseous isothermal systems with the chemical reaction 7. Calculation of the equilibrium conditions in heterogeneous systems with the chemical reaction 8. Calculation of the equilibrium composition of the reaction mixture in isothermal system 9. Calculation of the equilibrium composition of the adiabatic system 10. Fundamental electrochemical equations. Conductivity of electrolytes, Faraday law, calculation of electrodes potential, reference electrodes 11. Calculation of current and thermodynamic efficiency of electrochemical process 12. Calculation of equilibrium and operating voltage of the electrolyzer 13. Calculation of equilibrium and operating voltage of the fuel cell 14. Calculation of equilibrium and operating voltage of the fuel cell, mass and energy balance
Last update: Paidar Martin (05.10.2017)
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http://eso.vscht.cz/ Last update: Paidar Martin (25.08.2015)
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