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The course deals with deeper understanding of structure, syntheses and applications of organoelement compounds containing less common non-transition elements of the second period (organoboron and organofluorine compounds), as well as of the third period (organosilicon, organophosphorus and organosulfur compounds). Apart of that, the attention is also paid to the detailed structure, syntheses and applications of selected organometallic (organolithium, organomagnesium and organocopper) compounds and hypervalent iodine compounds. The emphasis is given to the novel structural aspects obtained by quantum chemistry studies, as well as on modern synthetic methods and understanding of their mechanisms.
Last update: Kvíčala Jaroslav (09.07.2018)
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Students will be able to: Understand principles of bonding in organoboron and organofluorine compounds, explain key mechanisms of syntheses and application reactions Understand principles of bonding in organosilicon, organophosphorus and organosulfur compounds, explain key mechanisms of syntheses and application reactions Understand principles of bonding in organolithium, organomagnesium and organocopper compounds, explain key mechanisms of syntheses and application reactions Understand principles of bonding in hypervalent iodine compounds, explain key mechanisms of syntheses and application reactions Last update: Kvíčala Jaroslav (09.07.2018)
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The subject is completed by an exam consisting of written and oral part. A student is qualified for a final exam after giving a presentation on a selected topic. Last update: Rybáčková Markéta (15.08.2024)
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R: Suzan E. Thomas: Organic Synthesis. The Roles of Boron and Silicon. Oxford University Press, Oxford 1991. ISBN10: 0198556624, ISBN13: 9780198556626.
R: M. Hudlický a A. Pavlath, ed.: Chemistry of Organic Fluorine Compounds II. ACS, Washington 1992. ISBN10: 084122515X, ISBN13: 9780841225152.
R: Gordon H. Whitham: Organosulfur Chemistry. Oxford University Press, Oxford 1991. ISBN10: 0198558996, ISBN13:9780198558996.
R: Louis D. Quin: A Guide to Organophosphorus Chemistry. Wiley & Sons, New York 2000. ISBN 0471318248. Last update: Rybáčková Markéta (15.08.2024)
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nejsou Last update: Kvíčala Jaroslav (09.07.2018)
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1. Principles of bonding in organoboron compounds 2. Mechanisms of syntheses and applications of organoboron compounds 3. Principles of bonding in organofluorine compounds 4. Mechanisms of syntheses and applications of organofluorine compounds 5. Principles of bonding in organosilicon compounds 6. Mechanisms of syntheses and applications of organosilicon compounds 7. Principles of bonding in organophosphorus compounds 8. Mechanisms of syntheses and applications of organophosphorus compounds 9. Principles of bonding in organosulfur compounds 10. Mechanisms of syntheses and applications of organosulfur compounds 11. Principles of bonding in organoselenium compounds, mechanisms of syntheses and applications 12. Principles of bonding in organolithium and organomagnesium compounds, mechanisms of syntheses and applications 13. Principles of bonding in organocopper compounds, mechanisms of syntheses and applications 14. Principles of bonding in hypervalent organoiodine compounds, mechanisms of syntheses and applications Last update: Kvíčala Jaroslav (09.07.2018)
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Electronic version of lectures Last update: Kvíčala Jaroslav (09.07.2018)
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None Last update: Kvíčala Jaroslav (09.07.2018)
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Inorganic chemistry, organic chemistry Last update: Kvíčala Jaroslav (09.07.2018)
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