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Organic Chemistry of Selected Elements - M110018
Title: Organická chemie vybraných prvků
Guaranteed by: Department of Organic Chemistry (110)
Faculty: Faculty of Chemical Technology
Actual: from 2020
Semester: winter
Points: winter s.:3
E-Credits: winter s.:3
Examination process: winter s.:
Hours per week, examination: winter s.:2/0, Ex [HT]
Capacity: 20 / unknown (unknown)
Min. number of students: unlimited
State of the course: taught
Language: Czech
Teaching methods: full-time
Level:  
Additional information: http://Předmět je vyučován jen v ZS
Note: course can be enrolled in outside the study plan
enabled for web enrollment
Guarantor: Kvíčala Jaroslav prof. Ing. CSc.
Classification: Chemistry > Organic Chemistry
Interchangeability : N110011
This subject contains the following additional online materials
Annotation -
The course Organic Chemistry of Selected Elements fills the gap between the Organic Chemistry course and the course Transition Metals in Organic Synthesis. It is targeted on properties, preparation and reactions of the compounds of specific 2nd period elements (organoboron and organofluorine chemistry), as well as of 3rd period elements (organosilicon, organophosphorus and organosulfur chemistry). Attention is also paid to structures and reaction mechanisms of both hard (organolithium, organomagnesium), and soft (organocuprates) organometallic compounds.
Last update: Pátková Vlasta (10.01.2018)
Course completion requirements -

The subject is completed by a writen exam. A student is qualified for a final exam after giving a presentation on a selected topic.

Last update: Rybáčková Markéta (15.08.2024)
Literature -

Recommended:

  • Thomas, Susan E.. Organic synthesis, the roles of boron and silicon. Oxford: Oxford Univ. Press, 1991, https://vufind.techlib.cz/Record/000903270 s. ISBN 0-19-855662-4.

  • Hudlický, Miloš, Pavláth, Attila. Chemistry of organic fluorine compounds II, a critical review. Washington: American Chemical Society, 1995, https://vufind.techlib.cz/Record/001882018 s. ISBN 0-8412-2515-X.

  • Whitham, Gordon H.. Organosulfur chemistry. Oxford: Oxford Univ. Press, 1995, https://vufind.techlib.cz/Record/000903271 s. ISBN 0-19-855899-6.

  • Quin, Louis D., Quin, Gyöngyi Szakál. A guide to organophosphorus chemistry. : , , https://vufind.techlib.cz/Record/001864861 s. ISBN 0-471-31824-8.

Last update: prepocet_literatura.php (19.12.2024)
Syllabus -

1. Overview of organic chemistry of 2nd row elements.

2. Properties and syntheses of organoboron compounds, hydroboration.

3. Reduction and homologation with organoboron compounds, boranes in neutron capture therapy, carboranes.

4. Properties of organofluorine compounds, introduction of fluorine, trifluoromethyl, perfluoroalkyl.

5. Fluorinated building blocks, applications of organofluorine compounds.

6. Principles of bonding in organic compounds of 3rd row elements, comparison with 2nd row elements.

7. Preparations and properties of organosilicon compounds.

8. Applications or organosilicon compounds, silicones.

9. Preparations and properties of organophosphorus compounds.

10. Applications of organophosphorus compounds, Wittig and Mitsunobu reactions.

11. Preparations and properties of organosulfur compounds.

12. Applications of organosulfur compounds, sulfur ylides, Julia reaction.

13. Preparations, properties and applications of organoselenium compounds.

14. Preparations, properties and applications of organolithium and organomagnesium compounds, organocuprates.

Last update: Pátková Vlasta (10.01.2018)
Learning resources -

Electronic version of lectures

Last update: Pátková Vlasta (10.01.2018)
Learning outcomes -

Students will be able to:

evaluate properties, synthesis and reactivity of organoboron compounds

evaluate properties, synthesis and reactivity of organofluorine compounds

evaluate properties, synthesis and reactivity of organoelement compounds of 3rd period (silicon, phosphorus and sulfur)

evaluate properties, synthesis and reactivity of hard (organolithium and organomagnesium) and soft (organocopper) organometals

Last update: Pátková Vlasta (10.01.2018)
Registration requirements -

No.

Last update: Kundrát Ondřej (10.01.2018)
Teaching methods
Activity Credits Hours
Účast na přednáškách 1 28
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 0.5 14
Příprava na zkoušku a její absolvování 1.5 42
3 / 3 84 / 84
 
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