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Thermodynamics of materials is an inseparable part of theoretical foundations of materials engineering. It deals with thermodynamic properties of solids and phase and chemical equilibria in heterogeneous systems. It allows to simulate various processes of materials preparation and treatment and so it contributes to better understanding of these processes and their optimization. This course proposes the above mentioned theme in slightly advanced form. Knowledge obtained within this course will be used in other materials related subjects in Mgr. study. Last update: Leitner Jindřich (20.02.2018)
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Acquiring credit for solving examples of individual projects of students, successful completion of the test (at least 40%) and passing the oral exam. Last update: Leitner Jindřich (20.02.2018)
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R:J.Leitner,P.Voňka:Termodynamika materiálů,Skripta VŠCHT,Praha,1992,8070801670 R:J.Leitner,P.Voňka:Termodynamika materiálů-příklady,Skripta VŠCHT,Praha,1997,8070802839 A:D.R.Gaskell,D.E.Laughlin: Introduction to Thermodynamics of Materials, 6th edition,CRC Press,2017,9781498757003 A:S.Stolen,T.Grande:Chemical Thermodynamics of Materials,John Wiley & Sons,2003,0471492302 Last update: Leitner Jindřich (20.02.2018)
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1. Thermodynamic functions and basic relations
2. Equation of state (p-V-T) and thermodynamic properties of solids
3. Phase equilibria in one-component system
4. Behavior of solutions - mixing and excess properties, ideal solutions
5. Excess properties in binary systems, model of regular solution, Redlich-Kister equation
6. Multicomponent dilute solutions, alternative standard states
7. Statistical model of solid solutions, lattice (Guggenheim) and sublattice (Hillert) models
8. Chemical equilibria of reactions involving pure condensed phases
9. (s)-(g) equilibria, Ellingham diagrams, Kellogg diagrams
10. Calculation of equilibrium composition of simple (s)-(g) heterogeneous systems
11. (s)-(l) and (s)-(s) equilibria of binary systems - construction and interpretation of phase diagrams
12. (s)-(l) and (s)-(s) equilibria of binary systems - calculation of equilibrium composition
13. Phase diagrams of ternary systems
14. Calculation of complex chemical equilibria in heterogeneous systems Last update: Leitner Jindřich (28.02.2018)
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http://onlinelibrary.wiley.com/book/10.1002/0470092688: Stolen,T.Grande:Chemical Thermodynamics of Materials (VSCHT E-zdroje) Last update: Leitner Jindřich (22.02.2018)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Konzultace s vyučujícími | 0.5 | 14 | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 0.5 | 14 | ||
Práce na individuálním projektu | 0.5 | 14 | ||
Příprava na zkoušku a její absolvování | 1 | 28 | ||
4 / 4 | 98 / 112 |