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Last update: Urban Štěpán prof. RNDr. CSc. (31.07.2019)
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Last update: Urban Štěpán prof. RNDr. CSc. (31.07.2019)
Students will be able: To describe and to explain the principles of the molecular spectroscopy methods on the basis of quantum mechanics and chemistry. To discuss the applications and validity of Lambert-Beerova law with regard to the basic physical principles. To apply the basic principles of group theory in spectroscopy. To describe applications of molecular spectroscopy in research and in analytical chemistry including methods for long-distance detections of molecules. |
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Last update: Urban Štěpán prof. RNDr. CSc. (31.07.2019)
Z: Modern Spectroscopy, J. Michael Hollas, J. Wiley&Sons, Ltd 2004, Chichester, England, ISBN 0 470 84416 7 Z:Handbook of Spectroscopy, Editor(s): Prof. Dr. Guenter Gauglitz, Prof. Dr. Tuan Vo-Dinh, Wiley-VCH 2003, Print ISBN: 9783527297825 Online ISBN: 9783527602308 DOI: 10.1002/3527602305 D:Frontiers of Molecular Spectroscopy, Edited by: Jaan Laane, Elsevier 2008, ISBN 9780444531759, http://www.sciencedirect.com/science/book/9780444531759 |
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Last update: Urban Štěpán prof. RNDr. CSc. (31.07.2019)
Materials in electronic form are available. |
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Last update: Urban Štěpán prof. RNDr. CSc. (31.07.2019)
1. Introduction. Population of quantum states. Einstein theory of spectral transitions. Planck law. 2. Radiation transfer equation and its special cases. Theoretical principles of quantitative analysis. 3. Basic principles of experimental spectroscopy. 4. Radiation sources, detectors, optical materials and other elements of spectroscopy instruments. 5. Molecular spectroscopy, common theoretical background. Hamiltonian. Born-Oppenheimer approximation. 6. Microwave spectroscopy. Rotational spectroscopy and molecular geometry. 7. Vibration spectroscopy. Cartesian and normal coordinates. Normal modes. 8. Chemical application of IR and Raman spectroscopy. Analytical applications. 9. Molecular symmetry. Application of group theory in spectroscopy. 10. NMR. 11. Quantum chemistry principles. Molecular orbitals. Transitions types. 12. Electronic spectroscopy. Qualitative and quantitative analysis. 13. Photoelectron spectroscopy (UPS, XPS, ESCA). 14. Advanced spectroscopy applications |
Teaching methods | ||||
Activity | Credits | Hours | ||
Konzultace s vyučujícími | 0.5 | 14 | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 0.5 | 14 | ||
Příprava na zkoušku a její absolvování | 1 | 28 | ||
3 / 4 | 84 / 112 |