SubjectsSubjects(version: 855)
Course, academic year 2019/2020
  
Organic Chemistry of Selected Elements - AP110007
Title: Organic Chemistry of Selected Elements
Guaranteed by: Department of Organic Chemistry (110)
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: English
Teaching methods: full-time
Level:  
For type: doctoral
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Kvíčala Jaroslav prof. Ing. CSc.
Interchangeability : D110011, P110007
Annotation -
Last update: Pátková Vlasta (19.11.2018)
The course deals with deeper understanding of structure, syntheses and applications of organoelement compounds containing less common non-transition elements of the second period (organoboron and organofluorine compounds), as well as of the third period (organosilicon, organophosphorus and organosulfur compounds). Apart of that, the attention is also paid to the detailed structure, syntheses and applications of selected organometallic (organolithium, organomagnesium and organocopper) compounds and hypervalent iodine compounds. The emphasis is given to the novel structural aspects obtained by quantum chemistry studies, as well as on modern synthetic methods and understanding of their mechanisms.
Aim of the course -
Last update: Pátková Vlasta (19.11.2018)

Students will be able to:

Understand principles of bonding in organoboron and organofluorine compounds, explain key mechanisms of syntheses and application reactions

Understand principles of bonding in organosilicon, organophosphorus and organosulfur compounds, explain key mechanisms of syntheses and application reactions

Understand principles of bonding in organolithium, organomagnesium and organocopper compounds, explain key mechanisms of syntheses and application reactions

Understand principles of bonding in hypervalent iodine compounds, explain key mechanisms of syntheses and application reactions

Literature -
Last update: Pátková Vlasta (19.11.2018)

R: Suzan E. Thomas: Organic Synthesis. The Roles of Boron and Silicon. Oxford University Press, Oxford 1991. ISBN10: 0198556624, ISBN13: 9780198556626.

R: M. Hudlický a A. Pavlath, ed.: Chemistry of Organic Fluorine Compounds II. ACS, Washington 1992. ISBN10: 084122515X, ISBN13: 9780841225152.

R: Gordon H. Whitham: Organosulfur Chemistry. Oxford University Press, Oxford 1991. ISBN10: 0198558996, ISBN13:9780198558996.

R: Louis D. Quin: A Guide to Organophosphorus Chemistry. Wiley & Sons, New York 2000. ISBN 0471318248.

Learning resources -
Last update: Pátková Vlasta (19.11.2018)

Electronic version of lectures

Requirements to the exam - Czech
Last update: Pátková Vlasta (19.11.2018)

nejsou

Syllabus -
Last update: Pátková Vlasta (19.11.2018)

1. Principles of bonding in organoboron compounds

2. Mechanisms of syntheses and applications of organoboron compounds

3. Principles of bonding in organofluorine compounds

4. Mechanisms of syntheses and applications of organofluorine compounds

5. Principles of bonding in organosilicon compounds

6. Mechanisms of syntheses and applications of organosilicon compounds

7. Principles of bonding in organophosphorus compounds

8. Mechanisms of syntheses and applications of organophosphorus compounds

9. Principles of bonding in organosulfur compounds

10. Mechanisms of syntheses and applications of organosulfur compounds

11. Principles of bonding in organoselenium compounds, mechanisms of syntheses and applications

12. Principles of bonding in organolithium and organomagnesium compounds, mechanisms of syntheses and applications

13. Principles of bonding in organocopper compounds, mechanisms of syntheses and applications

14. Principles of bonding in hypervalent organoiodine compounds, mechanisms of syntheses and applications

Entry requirements -
Last update: Pátková Vlasta (19.11.2018)

None

Registration requirements -
Last update: Pátková Vlasta (19.11.2018)

Inorganic chemistry, organic chemistry

Course completion requirements -
Last update: Pátková Vlasta (19.11.2018)

Achieving 70% points from written test and successful passing the oral exam, defence of the project targeted to selected reaction.

 
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