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Last update: Kolafa Jiří prof. RNDr. CSc. (08.02.2018)
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Last update: Kolafa Jiří prof. RNDr. CSc. (08.02.2018)
STUDENTS WILL KNOW: How to solve moderately complex problems in chemical kinetics, electrochemistry and equilibria in ionic solutions. Forces between molecules and the consequences for the behavior of micro-and nano-objects. Fundamentals of the kinetic theory of gases. Fundamentals of the physical chemistry of polymers and surfaces. |
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Last update: Pátková Vlasta (15.01.2018)
A: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 A: Rubinstein M., Colby R.H., Polymer physics, Oxford University Press, 2010, 978-0-19-852059-7 |
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Last update: Pátková Vlasta (15.01.2018)
http://old.vscht.cz/fch/cz/pomucky/kolafa/N403041.html (lectures and links) |
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Last update: Kolafa Jiří prof. RNDr. CSc. (08.02.2018)
Lectures, homework (solved using a mathematical assistant as Maple), exercises (using Maple) |
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Last update: Kolafa Jiří prof. RNDr. CSc. (08.02.2018)
1. Formal chemical kinetics: simple and simultaneous reactions, catalysis. 2. Reaction mechanisms, chain reactions. Photochemical reactions. 3. Overview of classical thermodynamics: Gibbs energy and the direction of chemical reaction, chemical equilibrium, van't Hoff equation. 4. Chemical equilibrium – application: pH, weak acids and bases and their salts, buffers, slightly soluble salts. 5. Introduction to statistical thermodynamics: pressure of ideal gas and the interpretation of temperature, Boltzmann probability, entropy. 6. Non-equilibrium thermodynamics: transport properties, Fick's laws, diffusivity, electrical conductivity. 7. Kinetic theory of gases: basic concepts, Knudsen diffusion and effusion, other transport properties. 8. Electrochemistry: galvanic cells, Nernst equation; membranes and electrical phenomena. 9. Electrical phenomena in ionic solutions: electrical double layer, Debye-Hückel theory. 10. Thermodynamics of mixtures. Osmosis and other colligative properties. 11. Polymer physics: structure and description, ideal chain and its characteristics. 12. Polymer Physics: good, bad and theta solvent, Flory's Theory. Chain as a fractal. 13. Phase equilibria: equations of state, classification of phase transitions; Hildebrand and Flory-Huggins theory. 14. Surface tension, homogeneous and heterogeneous nucleation. |
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Last update: Pátková Vlasta (15.01.2018)
Physical Chemistry I |
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Last update: Řehák Karel doc. Ing. CSc. (02.03.2018)
Acquiring credit (meeting the minimum requirements of the computational part) The exam test |
Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
Práce na individuálním projektu | 0.5 | 14 | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
Účast na seminářích | 1 | 28 | ||
6 / 6 | 168 / 168 |