SubjectsSubjects(version: 877)
Course, academic year 2020/2021
  
Active sites from atoms to clusters in nanoporous matrices and their application - D105027
Title: Aktivní centra od atomů po klastry v nanoporézních matricích a jejich aplikace
Guaranteed by: Department of Inorganic Technology (105)
Actual: from 2017
Semester: both
Points: 10
E-Credits: 10
Examination process:
Hours per week, examination: 2/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level: specialized
For type: doctoral
Note: course is intended for doctoral students only
you can enroll for the course in winter and in summer semester
Guarantor: Dědeček Jiří Mgr. CSc. DSc.
Annotation -
Last update: Kubová Petra Ing. (27.11.2015)
The course is focused on the preparation and characterization of active sites (protons, cations, clusters) localized in nanoporous matrices of zeolites (and related materials) mesoporous molecular sieves and MOFs (metal organic frameworks) and their application in catalysis, separations and high-tech.
Aim of the course -
Last update: Kubová Petra Ing. (27.11.2015)

Students will be able to:

Describe the structure of micro- and mesoporous inorganic matrices and active sites localized in these matrices.

Describe methods of synthesis of individual types of micro- and mesoporous inorganic materials, of their modifications and of the formation of active sites on an atomic level.

Suggest approaches for the characterization of active sites of different structure localized in individual micro- and mesoporous inorganic matrices.

Describe the knowledge base of the application of processes employing active sites in micro- and mesoporous inorganic matrices in catalysis, separation and high-tech.

Literature -
Last update: Kubová Petra Ing. (27.11.2015)

A.W. Chester, E.G. Derouane: Zeolite Characterization and Catalysis, Springer 2009.

M. Che, J.C. Vedrine: Characterization of Solid Materials and Heterogeneous Catalysis 1, 2, Wiley-VCH2012.

J. Weitkamp, L. Puppe: Catalysis and Zeolites, Springer 1999.

J. Čejka, J. Perez-Pariente, W.J. Roth: Zeolites: from Model Materials to Industrial Catalysts, transwork Research Network, 2008.

Syllabus -
Last update: Kubová Petra Ing. (27.11.2015)

1.Zeolites, zeotypes a and their amorphous analogues (from the pore structure to the structure on atomic level)

2.Mesoporous molecular sieves

3.MOFs (metal-organic frameworks)

4.Framework and extraframework centers in micro- and mesoporous inorganic matrices, defects

5.Synthesis of micro- and mesoporous inorganic materials

6.Modification of micro- and mesoporous inorganic materials

7.Methods of characterization of active sites (protons, cations, clusters) localized in matrices and of matrices

8.Application of matrices with active sites in acidobasic catalysis

9. Application of matrices with active sites in redox catalysis

10. Application of matrices with active sites in sorption, separation, gas storage and high-tech (sensors, optoelectronic devices, luminescence)

Coursework assessment
Form Significance
Oral examination 100

 
VŠCHT Praha