Physical Organic Chemistry - D110001
Title: Fyzikální organická chemie
Guaranteed by: Department of Organic Chemistry (110)
Faculty: Faculty of Chemical Technology
Actual: from 2017 to 2021
Semester: summer
Points: summer s.:0
E-Credits: summer s.:0
Examination process: summer s.:
Hours per week, examination: summer s.:0/0, other [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
For type:  
Note: course is intended for doctoral students only
Guarantor: Böhm Stanislav doc. Ing. CSc.
Is interchangeable with: AP110001, P110001
Examination dates   
Annotation -
Last update: Böhm Stanislav doc. Ing. CSc. (24.04.2014)
The aim of this course is to acquire knowledge about mechanism of organic reactions based on the analysis of structural and electronic factors present in reactants and products.
Aim of the course -
Last update: Böhm Stanislav doc. Ing. CSc. (24.04.2014)

Students will be able to :

understand basic concept of physical organic chemistry

use of various methods of study of reaction mechanisms

understand reaction mechanisms of common chemical reactions

elucidate the relations between structure and reactivity of organic compounds

Literature -
Last update: Cibulka Radek prof. Ing. Ph.D. (04.09.2015)

R: Böhm S. : Fyzikální organická chemie, CD verze učebního textu

A: Eric V. Anslyn, Dennis A. Dougherty : Modern Physical Organic Chemistry 2004. ISBN 1891389319.

Learning resources -
Last update: Böhm Stanislav doc. Ing. CSc. (24.04.2014)

Lectures on CD

Syllabus -
Last update: Böhm Stanislav doc. Ing. CSc. (24.04.2014)

1. Structure and mechanism

2. Kinetic studies

3. Linear Gibbs energy relations

4. Acids and bases

5. The reaction medium

6. MO theory

7. Aliphatic nucleophilic substitution

8. Elimination reactions

9. Addition to C=C double bonds

10.Aromatic electrophilic substitution

11.Addition to C=O group and related reactions

12.The hydrolysis of carboxylic esters

13.Aromatic nucleophilic substitution

14.Molecular rearrangements

15.Aliphatic radical substitution

16.Pericyclic reactions

Registration requirements -
Last update: Böhm Stanislav doc. Ing. CSc. (24.04.2014)

Organic Chemistry I + II

Physical Chemistry I + II

Course completion requirements -
Last update: Cibulka Radek prof. Ing. Ph.D. (10.05.2014)

It is compulsory to pass written examination test with the result at least 50%, and finally to pass successfuly the oral examination.

Coursework assessment
Form Significance
Oral examination 100