SubjectsSubjects(version: 861)
Course, academic year 2019/2020
  
Chemical Thermodynamics for Oil Treatment - D403011
Title: Chemická termodynamika pro zpracování ropy
Guaranteed by: Department of Physical Chemistry (403)
Actual: from 2018
Semester: winter
Points: winter s.:7
E-Credits: winter s.:7
Examination process: winter s.:
Hours per week, examination: winter s.:0/0 other [hours/week]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type:  
Note: course is intended for doctoral students only
can be fulfilled in the future
Guarantor: Řehák Karel doc. Ing. CSc.
Z//Is interchangeable with: AP403010, P403010
Annotation -
Last update: Řehák Karel doc. Ing. CSc. (11.04.2018)
The course is focused on basic chemical-engineering calculations. Utilizations of equations of state and thermodynamic models which are implemented in chemical-engineering simulators are demonstrated. Theory background for calculations and basic equations are given in lectures. Computational skills are taught with the help of the Maple software. Real behaviour of fluids is usually considered in computational problems which are mainly focused on oil treatment.
Aim of the course -
Last update: Řehák Karel doc. Ing. CSc. (11.04.2018)

Students will be able to:

  • calculate state behaviour of real fluids and mixtures
  • calculate phase equilibria in two-component systems (considering real behaviour)
  • solve chemical equilibrium in simplified systems

(all calculations performed in the Maple software or Wolfram Mathematica)

Literature -
Last update: Řehák Karel doc. Ing. CSc. (11.04.2018)

R: J.M. Prausnitz, R.N. Lichtenthaler, E.G. Azevedo, Molecular thermodynamics of fluid-phase equilibria, Prentice-Hall PTR, 1999. 9780139777455

R: Novák J. a kol., Fyzikální chemie - bakalářský a magisterský kurz, VŠCHT, Praha 2008, 9788070806753

R: Novák J., Růžička K., Chemická termodynamika I, Stavové chování a termodynamické vlastnosti reálných tekutin, Vysoká škola chemicko-technologická, Praha 2002, 8070805013

R: Dohnal V., Novák J., Matouš J.: Chemická termodynamika II, Vysoká škola chemicko-technologická, Praha 1996, 8070802758

A: Riazi M.R., Characterization And Properties Of Petroleum Fractions, ASTM International, 2005, Philadelphia, 2005, 0803133618

A: Růžička V., Odhadové metody pro fyzikálně-chemické vlastnosti tekutin, Vysoká škola chemicko-technologická, Praha 1996, 8070802561

Syllabus -
Last update: Řehák Karel doc. Ing. CSc. (11.04.2018)

1. State behaviour of real mixtures of pure fluids, critical quantities and their prediction

2. Equations of state of real fluids, theorem of corresponding states

3. State behaviour of real mixtures

4. Virial equation of state, prediction of virial coefficients.

5. Thermodynamic properties of fluids, calculation of heat and work in typical processes.

6. Residual molar quantities and their applications.

7. Thermodynamic properties of components in mixtures. Excess quantities.

8. Activity and activity coefficients. Thermodynamic models for excess Gibbs energy

9. Vapour-liquid equilibria at low and high pressures, determination and prediction.

10. Solubility of gases in liquids

11. Liquid-liquid equilibria

12. Liquid-solid equilibria

13. Chemical equilibrium of simple systems.

14. Chemical equilibrium of complex systems.

Registration requirements -
Last update: Řehák Karel doc. Ing. CSc. (11.04.2018)

Physical Chemistry II

Teaching methods
Activity Credits Hours
Účast na přednáškách 1 28
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1 28
Práce na individuálním projektu 2 56
Příprava na zkoušku a její absolvování 2 56
Účast na seminářích 1 28
7 / 7 196 / 196
 
VŠCHT Praha