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Last update: Fialová Jana (04.01.2018)
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Last update: Fialová Jana (04.01.2018)
Students will be able to: design the structure of artificial receptor for the complexation of cation or anion select suitable analytical method for the study of the structure of the complex suggest suitable analytical/spectroscopic methods for the measuring of the complexation constants and thermodynamic parameters for selected host-guest processes apply the principals of "self-assembly" for the synthesis of topological isomers use the principals of supramolecular chemistry in the advanced organic synthesis |
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Last update: Fialová Jana (04.01.2018)
R: Jonathan W. Steed, Jerry L. Atwood: Supramolecular Chemistry, 2nd Edition, Wiley 2009. 9780470512340 A: Beer P. D., Gale P. A., Smith D. K.: Supramolecular Chemistry, Oxford Chemistry Primers, Oxford University Press 1999. 0198504470 A: Diderich F., Stang P. J., Tykwinski R. R. (Eds.): Modern Supramolecular Chemistry, Wiley 2008, ISBN: 978-3-527-31826-1. A: Lhoták P., Stibor I.: Molekulární Design; vysokoškolská skripta, vydavatelství VŠCHT Praha, 1997. 8070802952 A: kolektiv autorů: Supramolekulární chemie I, Cyklus Organická Chemie, svazek 29, 2004, ÚOCHB Praha. 8086241211 A: kolektiv autorů: Supramolekulární chemie II, Cyklus Organická Chemie, Svazek. 30, UOCHB AV ČR Praha, 2005. 8086241270 |
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Last update: Fialová Jana (04.01.2018)
Electronic materials available at the lecturer |
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Last update: Fialová Jana (04.01.2018)
1. What is supramolecular chemistry? Introduction and basic definitions. Chemistry of crownethers - complexation of cationts 2. Noncovalent intermolecular interactions 3. Anion complexation 4. Binding of neutral molecules, chiral recognition 5. Modular approach - the coordination chemistry of bipyridines 6. Calix[n]arenes and related macrocycles 7. Cyclodextrins, cucurbiturils, cyclotriveratrylenes 8. Chemistry of fullerenes, carbon nanotubes and other carbon allotropes 9. Dendrimers 10. The evaluation of the complexation ability - complexation constants 11. Self-assembly 12. Topological isomers (rotaxanes, catenanes, knotanes), nanomachines 13. Liquid crystals 14. Surfactants and interfacial ordering |
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Last update: Kundrát Ondřej Ing. Ph.D. (08.01.2018)
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Last update: Kundrát Ondřej Ing. Ph.D. (15.02.2018)
The subject is completed by the written and oral examination. A student is qualified for a final exam after obtaining credit and after giving 10 min presentation on a selected topic.
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1 | 28 | ||
Práce na individuálním projektu | 0.5 | 14 | ||
Příprava na zkoušku a její absolvování | 2 | 56 | ||
Účast na seminářích | 0.5 | 14 | ||
4 / 4 | 112 / 112 |