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Last update: TAJ101 (03.12.2013)
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Last update: Hoskovcová Irena Ing. CSc. (08.08.2018)
Students will be able to: Use the basic coordination chemistry notions Distinguish access CFT, LFT and MO theory, know their advantages and applicability limits Explain the typical properties of coordination compounds using an appropriate model Understand the primary literature and monographs |
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Last update: TAJ101 (26.08.2013)
R: J. Ribas Gispert: Coordination Chemistry, Wiley-VCH, 2008, ISBN: 978-3-527-31802-5 A: Y. Jean: Molecular Orbitals of Transition Metal Complexes, OxfordUP, 2005, ISBN: 0-19-853093-5 A: R. Boča: Chémia koordinačných a organokovových zlúčenín, Nakladatelství STU, 2009, ISBN: 978-80-227-3082-2 A: příslušné kapitoly v učebnicích (Housecroft-Sharp, Cotton-Wilkinson, Jolly, Wulfsberg, Greenwood-Earnshaw) |
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Last update: Hoskovcová Irena Ing. CSc. (08.08.2018)
https://e-learning.vscht.cz/course/view.php?id=128 http://www.vscht.cz/ach/vyuka-magisterske-koordch.html http://wwwchem.uwimona.edu.jm:1104/courses/Tanabe-Sugano/ |
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Last update: Hoskovcová Irena Ing. CSc. (16.09.2016)
Each week tasks related to actual topic is given. To obtain the credit the students should have to at least 7 times independently resolved this tasks. The exam is oral. |
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Last update: Hoskovcová Irena Ing. CSc. (19.11.2012)
1. History of coordination chemistry 2. Crystal Field Theory, Ligand Field Theory. 3. Molecular orbitals in coordination compounds. 4. Coordination polyhedra, fluxionality. Continuous symmetry concept.. 5. Isomerism. Description ad determination of the absolute configuration. 6. Stability of coordination compounds, mechanisms of ligand substitution. 7. Ligands and their classification: nature of donor atoms, bonding possibilities. Chelates. 8. Metal � ligand interaction from the Lewis acid-base theory’s point of view. 9. Allyl complexes, metallocenes, cyclic ligands, template effect. 10. Polynuclear complexes, clusters. 11. Changes of ligand properties and reactivity after coordination to a metal centre. 12. Spectroscopy of coordination compounds. Photochemical reactions. 13. Magnetic properties of coordination compounds. Molecular magnets. 14. Electron transfer mechanisms.
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Last update: TAJ101 (26.08.2013)
General and Inorganic Chemistry II |
Teaching methods | ||||
Activity | Credits | Hours | ||
Konzultace s vyučujícími | 0.5 | 14 | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
Účast na seminářích | 1 | 28 | ||
6 / 6 | 168 / 168 |
Coursework assessment | |
Form | Significance |
Regular attendance | 40 |
Oral examination | 60 |