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The course builds on Carbonaceous materials subject and shows processes for the production of basic organic products and intermediates. It is organize by processes, rather than products, allowing accentuating the common production features. All processes follow a uniform structure, beginning with the reactions overview, continuing with the interpretation of kinetic and thermodynamic aspects, catalysts and information on the technical implementation, and the examples of processes - simple basic technology of selected substances.
Last update: TAJ111 (29.08.2013)
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Students will be able to:
Last update: TAJ111 (29.08.2013)
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R: Červený L., Hronec M., Koubek J., Kurc L., Pašek J., Volf J.:Základní pochody průmyslové organické chemie, Skriptum, VŠCHT Praha 1993 a další vydání, 80-7080-171-9 A: Weissermel K., Arpe H.J.: Průmyslová organická chemie, SNTL, Praha 1984 a další vydání A: Moulijn J.A., Makkee M., Van Diepen A.: Chemical Process Technology, John Wiley, 2001, 0-471-63062-4 Last update: TAJ111 (29.08.2013)
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2 testy v průběhu semestru, ústní zkouška Last update: TAJ111 (24.02.2009)
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1. Introduction to the subject. Survey of hydrogenation and dehydrogenation processes 2. Chemical equilibrium and kinetics of hydrogenation and dehydrogenation processes 3. Technical aspects of hydrogenation and dehydrogenation processes 4. Survey of oxidations. Amoxidation 5. Kinetics and mechanism of oxidation, catalytic systems 6. Technical aspects of oxidation. Examples of typical processes 7. Halogenation, mechanism, kinetics and selectivity of chlorination 8. Technical aspects of chlorination, examples of typical processes 9. Fluorization, bromination. Feasible degradation of organic halogencompounds, environmental issues. 10. Sulfonation and sulfatation, nitration - survey of reactions, technical aspects 11. Amonolysis and hydrolysis - kinetics, mechanism, examples of processes 12. Esterification, survey of acid-catalysed reactions, examples of processes 13. Alkylation - mechanism, kinetics, technology 14. Reactions catalysed by metal complexes. Hydroformylation, methatesis Last update: TAJ111 (29.08.2013)
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http://onlinelibrary.wiley.com/book/10.1002/14356007 http://scholar.google.cz/ Last update: TAJ111 (29.08.2013)
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Organic chemistry I, Physical chemistry I Last update: TAJ111 (29.08.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Konzultace s vyučujícími | 0.5 | 14 | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
5 / 5 | 140 / 140 |
Coursework assessment | |
Form | Significance |
Regular attendance | 10 |
Continuous assessment of study performance and course -credit tests | 20 |
Oral examination | 70 |