SubjectsSubjects(version: 953)
Course, academic year 2021/2022
Physical Chemistry I - N403011
Title: Fyzikální chemie I
Guaranteed by: Department of Physical Chemistry (403)
Faculty: Faculty of Chemical Engineering
Actual: from 2021
Semester: winter
Points: winter s.:6
E-Credits: winter s.:6
Examination process: winter s.:
Hours per week, examination: winter s.:3/2, C+Ex [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
State of the course: cancelled
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
Is provided by: B403003
Additional information:
Guarantor: Řehák Karel doc. Ing. CSc.
Class: Předměty pro fyzikální chemii
Interchangeability : N403011A, N403032, N403035, Z403011
Is incompatible with: B403016, N403032
Is interchangeable with: B403003, AB403003, N403011A
Examination dates   Schedule   
Annotation -
The subject covers elementary parts of physical chemistry (i.e. basic ideas and quantities, state behaviour, fundamentals of thermodynamics) which are followed by chapters on phase equlibria and chemical equilibria. Basic principles of behaviour and properties of electrolytes are introduced. The final part is devoted to kinetics of chemical reactions.
Last update: TAJ403 (11.08.2013)
Aim of the course -

Students will be able to:

  • calculate the state behaviour of gases at low pressures,
  • use basic thermodynamic functions,
  • calculate heats of reactions and solve chemical equilibrium for simple reactions,
  • understand basic phase equilibrium diagrams and solve vapour-liquid equilibrium for ideal systems,
  • calculate basic types of chemical kinetics

Last update: TAJ403 (31.07.2013)
Literature -

A: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373

Last update: KNOBLOCL (17.12.2015)
Learning resources -

Last update: TAJ403 (31.07.2013)
Teaching methods -

Lectures and seminar meetings.

Last update: TAJ403 (31.07.2013)
Requirements to the exam -

The participants will be informed at the first meeting.

See also

Last update: TAJ403 (31.07.2013)
Syllabus -

1. Basic terminology, thermodynamic system, thermodynamic process, state properties.

2. State behaviour of gases, equation of state of ideal gas. Real gas and its behaviour.

3. 1st law of thermodynamics. Internal energy, heat, work.

4. Enthalpy, heat of reaction, standard enthalpy of formation. Hess and Kirchhoff's laws.

5. 2nd law of thermodynamics, entropy. Entropy changes on selected processes.

6. Helmholtz and Gibbs energy, their significance. 3rd law of thermodynamics.

7. Partial molar quantities, activity, chemical potential, standard states.

8. Phase equilibria in single-component systems, Clapeyron equation.

9. Gibbs phase law, vapour-liquid equilibrium in ideal systems, phase diagrams.

10.Solubility of gases in liquids, equilibria in condensed systems.

11.Material balance of chemical reactions. Equilibrium constant. Equilibria in electrolyte systems.

12.Equilibrium composition. Reactions in gaseous phase.

13.Faraday´s law, galvanic cells, Nernst equation.

14.Basic terms of chemical kinetics, reaction rate, integration of rate equations.

Last update: TAJ403 (28.12.2005)
Entry requirements -

The basic course of mathematics and physics for batchelor study.

Last update: TAJ403 (25.01.2008)
Registration requirements -

Mathematics I, Physics I

Last update: TAJ403 (31.07.2013)
Teaching methods
Activity Credits Hours
Účast na přednáškách 1.5 42
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1.5 42
Příprava na zkoušku a její absolvování 2 56
Účast na seminářích 1 28
6 / 6 168 / 168
Coursework assessment
Form Significance
Examination test 40
Continuous assessment of study performance and course -credit tests 50
Oral examination 10