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The aim of the course is to familiarise students with the chemical engineering description of phenomena, laboratory and industrial processes during which dispersions or other structured multiphase systems are formed or play a crucial role.
Last update: Štěpánek František (25.09.2013)
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After completing the course, the students will be able to:
Last update: Štěpánek František (01.10.2013)
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R: R.F. Probstein, Physicochemical hydrodynamics, Wiley, 1994
R: L.L. Schramm, Emulsions, Foams and Suspensions, Wiley, 2005 Last update: SEK409 (09.10.2013)
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1. Classification of dispersion systems (emulsions, suspensions, foams...). Particle size distributions, moments.
2. Particle size measurement. Sampling, segregation.
3. Force interactions in particle systems. Electrostatic and osmotic interactions in liquid dispersion systems.
4. Adhesion mechanisms, van der Waals forces, electrostatic forces, capillary forces. Adhesion and surface roughness. Adhesion forces and energies.
5. Dynamics of coagulation and coalescence. DLVO theory, Ostwald ripening. Kinetic and thermodynamic stability of emulsions.
6. Overview of technologies for the preparation of dispersions. Classification according to the type of dispersion and the physical mechanism.
7. Preparation of aerosols. Nucleation and coagulation of particles. Electrospray and spray drying.
8. Extraction with partially miscible solvents. Phase diagrams of water-oil-surfactant systems.
9. HLB of surfactants, preparation of w/o and o/w emulsions. Stability of emulsions. Examples of emulsions.
10. Dispersions of solid particles. Sol-gel methods, precipitation. Colloidal crystals.
11. Emulsion polymerization. Nucleation, stability of emulsions.
12. Porous materials, percolation. Texture analysis, diffusion and sorption in porous media.
13. Foam materials with open and closed cells. Thermal and sound insulation properties of foam materials.
14. Preparation of nanofibres Electrospinning, extrusion. Last update: Štěpánek František (25.09.2013)
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http://www.vscht.cz/uchi/ped/index.html Last update: Štěpánek František (25.09.2013)
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Physics I Last update: Štěpánek František (25.09.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast v laboratořích (na exkurzi nebo praxi) | 2 | 56 | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 2 | 56 | ||
Příprava na zkoušku a její absolvování | 1 | 28 | ||
Účast na seminářích | 1 | 28 | ||
7 / 7 | 196 / 196 |
Coursework assessment | |
Form | Significance |
Examination test | 50 |
Oral examination | 50 |