SubjectsSubjects(version: 877)
Course, academic year 2020/2021
  
Thermodynamic properties of inorganic substances - P101001
Title: Termodynamické vlastnosti anorganických látek
Guaranteed by: Department of Inorganic Chemistry (101)
Actual: from 2020
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Sedmidubský David prof. Dr. Ing.
Z//Is interchangeable with: AP101001
Annotation -
Last update: Sedmidubský David prof. Dr. Ing. (15.11.2018)
The course is based on essential principles of general and inorganic chemistry, physical chemistry and solid state chemistry and extends the knowledge and skills acquired in the master subject Energetics of Inorganic Substances. It opens a wau to a deeper understanding of energy role in chemical processes. The students will check their ability to assess the reactivity and stability of substances.
Aim of the course -
Last update: Sedmidubský David prof. Dr. Ing. (15.11.2018)

Students will be able:

Interpret the origin and significance of enthalpy and entropy contributions to the properties of inorganic substances.

Assess the effect of nomalous conditions on the energetic behavior of matter.

Estimate the existance probability of a given substance/phase.

Interpert the ions behavior in aqueous solutions.

Interpret the periodic trends in thermodynamic properties of compounds.

Literature -
Last update: Sedmidubský David prof. Dr. Ing. (16.11.2018)

R: Dasent W.E.:Inorganic Energetics: an Introduction, Cambridge University Press, 1982

A: Johnson D.A.:Some Thermodynamic Aspects of Inorganic Chemistry, Cambridge University Press, 1982

A: Wulfsberg G.:Inorganic Chemistry, University Science Books, 2000?1-891389-01-7

Syllabus -
Last update: Sedmidubský David prof. Dr. Ing. (15.11.2018)

1. Basic laws of the thermodynamics.

2. The scope of stability and instability of chemical systems. kinetics.

3. Strucure and properties of gaseous atoms, ions and molecules.

4. Born-Haber cycle and bonding energy.

5. Chemical cycles in inorganic chemistry

6. Madelung konstant and Kapustinskij equation in estimation of ΔGof for ionic compounds

7. Covalent and molecular crystals.

8. Problems in the estimation of bond energy in covalent compounds

9. Cohesive energy of sytems with metallic bond.

10.Solubility of ionic crystals. Hydrolysis and hydratation.

11.Electrochemistry of inorganic compounds

12.Broenstedt-Lowry theory of inorganic acids and bases.

13.Factors influencing the stability of coordination compounds.

14.Type of bond, structure and properties of inorganic substances.

 
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