SubjectsSubjects(version: 861)
Course, academic year 2019/2020
  
Reactivity and Structure Characteristics of Solid Materials - P105002
Title: Reaktivita a strukturní charakteristiky pevných látek
Guaranteed by: Department of Inorganic Technology (105)
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: course is intended for doctoral students only
you can enroll for the course in winter and in summer semester
Guarantor: Fíla Vlastimil doc. Dr. Ing.
Lhotka Miloslav Ing. Ph.D.
Interchangeability : D105006
Z//Is interchangeable with: AP105002
Annotation -
Last update: Pátková Vlasta (17.04.2018)
This course is designed to provide the fundamentals of fluid - solid surfaces phenomena, including detailed discussion of the experimental characterisation techniques used both for structural and chemical properties of solid surfaces. Adsorption, catalytic activation and flow phenomena in porous structures are discussed. Specific applications to catalytic engineering, electrochemistry, and material sciences are investigated.
Aim of the course -
Last update: Pátková Vlasta (17.04.2018)

Students will be able to:

Describe the basic phenomena occurring at the solid-liquid interface

Design optimal experimental method to characterize the structure and chemical composition of solid surfaces

Identify and calculate the basic textural characteristics of catalysts

Combine phenomena of adsorption, catalytic activation and transport in porous media with industrially important applications in catalysis, electrochemistry and material science.

Literature -
Last update: Pátková Vlasta (17.04.2018)

R:S.Lowell, J. E. Shields, M. A. Thomas and M. Thommes: Characterization of porous Solids and Powders: Surface Area, Pore Size and Density, Kluwer Academic Publisher, Dordrecht 2004

A:P. Webb and C.Orr: Analytical Methods in Fine Partical Technology,Micromeritics, Norcross 1997

A:Morrison S.R.: The Chemical Physics of Surfaces, Plenum Press N.Y. 1977

A:Attard G., Barnes C.: Surfaces, Oxford University Press 1998

Learning resources -
Last update: Pátková Vlasta (17.04.2018)

Applied Surface Science: http://www.sciencedirect.com/science/journal/01694332

Teaching methods -
Last update: Lhotka Miloslav Ing. Ph.D. (27.06.2018)

lectures

Requirements to the exam -
Last update: Lhotka Miloslav Ing. Ph.D. (27.06.2018)

none

Syllabus -
Last update: Sedlářová Ivona Ing. Ph.D. (28.06.2018)

Subject is focused on the following topics:

1. Surface characteristics of solids, classification of methods

2. Geometric and textural characteristics of solid surface, the thermodynamics of phase boundaries, adsorption isotherms

3. Size distribution of mesopores, adsorption method, size distribution of micropores, adsorption method, immersion calorimetry

4. Mercury porosimetry, size distribution of macropores

5. Electron spectroscopy ESCA, principle, apparatus

6. Auger and some other electron spectroscopies, SIMS, electron microscopy and microprobe, examples of application

7. Surface structure, electron diffraction methods

8. Models of chemisorption on ionic crystals and semiconductors

9. Catalytic activation of simple molecules (N2,O2,H2,CO)

10. Mechanism of transport in porous materials, membrane processes

11. Catalytic processes in porous materials

Entry requirements -
Last update: Lhotka Miloslav Ing. Ph.D. (27.06.2018)

none

Registration requirements -
Last update: Lhotka Miloslav Ing. Ph.D. (27.06.2018)

none

Course completion requirements -
Last update: Pátková Vlasta (17.04.2018)

Completing a course is an oral exam. The requirement for an oral exam is a graduation test calculation and a project to advance the topic.

Coursework assessment
Form Significance
Examination test 20
Oral examination 80

 
VŠCHT Praha