SubjectsSubjects(version: 855)
Course, academic year 2019/2020
  
Phase and Chemical Equilibrium in Chemical Technology - P105010
Title: Fázové a chemické rovnováhy v chemické technologii
Guaranteed by: Department of Inorganic Technology (105)
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: you can enroll for the course in winter and in summer semester
Guarantor: Krýsa Josef prof. Dr. Ing.
Is interchangeable with: AP105010
Annotation -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)
The content of the subject is the description of phase equilibriums and chemical thermodynamics, particularly following the separation and chemical processes in the chemical technology.
Aim of the course -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

Students will be able to:

Describe phase equilibrium in solid-liquid, liquid-vapor and liquid – liquid systems.

Calculate the equilibrium composition of the reaction mixture in homogeneous systems (gaseous phase) and in heterogeneous systems (solid phase-gas)

Literature -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

Prausnitz, J. M.; Lichtenthaler, R. N.; de Azevedo, E. G. Molecular Thermodynamics of Fluid-Phase Equilibria. Prentice Hall: 3 ed.; 1998.

M. Malinovský, I.Roušar a kol., Teoretické základy pochodů anorganické technologie, SNTL/ALFA, 1987

Learning resources -
Last update: Krýsa Josef prof. Dr. Ing. (02.07.2018)

https://old.vscht.cz/fch/en/tools/breviary.html

https://en.wikipedia.org/wiki/Phase_rule

https://en.wikipedia.org/wiki/Thermodynamics

https://en.wikipedia.org/wiki/Chemical_equilibrium

Teaching methods -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

lectures

Requirements to the exam -
Last update: Sedlářová Ivona Ing. Ph.D. (26.06.2018)

none

Syllabus -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

The subject is focused on the following topics:

1. Solid-liquid phase equilibrium, two-component system

2. Solid-liquid phase equilibrium, three-component system, graphical representation.

3. Solid-liquid phase equilibrium, four-component system, graphical representation

4. Gas-liquid phase equilibrium

5. Liquid-liquid phase equilibrium

6. State behavior of gases, relations for real behavior of the gas mixture.

7. Basic principles of chemical thermodynamics, reaction enthalpy, reaction Gibbs energy

8. Equilibrium composition for homogeneous systems-reactions in the gas phase.

9. Equilibrium composition for heterogeneous systems (gas-solid phase).

10. Simultaneous chemical equlibrium

11. Adiabatic balance for chemical reaction. Limitation by equilibrium.

Entry requirements -
Last update: Sedlářová Ivona Ing. Ph.D. (26.06.2018)

none

Registration requirements -
Last update: Sedlářová Ivona Ing. Ph.D. (26.06.2018)

none

Course completion requirements -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

Oral exam

Coursework assessment
Form Significance
Oral examination 100

 
VŠCHT Praha