SubjectsSubjects(version: 954)
Course, academic year 2023/2024
  
Phase and Chemical Equilibrium in Chemical Technology - P105010
Title: Fázové a chemické rovnováhy v chemické technologii
Guaranteed by: Department of Inorganic Technology (105)
Faculty: Faculty of Chemical Technology
Actual: from 2020
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0, other [HT]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
State of the course: taught
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
Level:  
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Krýsa Josef prof. Dr. Ing.
Is interchangeable with: AP105010
Annotation -
The content of the subject is the description of phase equilibriums and chemical thermodynamics, particularly following the separation and chemical processes in the chemical technology.
Last update: Krýsa Josef (29.06.2018)
Aim of the course -

Students will be able to:

Describe phase equilibrium in solid-liquid, liquid-vapor and liquid – liquid systems.

Calculate the equilibrium composition of the reaction mixture in homogeneous systems (gaseous phase) and in heterogeneous systems (solid phase-gas)

Last update: Krýsa Josef (29.06.2018)
Literature -

Prausnitz, J. M.; Lichtenthaler, R. N.; de Azevedo, E. G. Molecular Thermodynamics of Fluid-Phase Equilibria. Prentice Hall: 3 ed.; 1998.

M. Malinovský, I.Roušar a kol., Teoretické základy pochodů anorganické technologie, SNTL/ALFA, 1987

Last update: Krýsa Josef (29.06.2018)
Learning resources -

https://old.vscht.cz/fch/en/tools/breviary.html

https://en.wikipedia.org/wiki/Phase_rule

https://en.wikipedia.org/wiki/Thermodynamics

https://en.wikipedia.org/wiki/Chemical_equilibrium

Last update: Krýsa Josef (02.07.2018)
Teaching methods -

lectures

Last update: Krýsa Josef (29.06.2018)
Requirements to the exam -

none

Last update: Sedlářová Ivona (26.06.2018)
Syllabus -

The subject is focused on the following topics:

1. Solid-liquid phase equilibrium, two-component system

2. Solid-liquid phase equilibrium, three-component system, graphical representation.

3. Solid-liquid phase equilibrium, four-component system, graphical representation

4. Gas-liquid phase equilibrium

5. Liquid-liquid phase equilibrium

6. State behavior of gases, relations for real behavior of the gas mixture.

7. Basic principles of chemical thermodynamics, reaction enthalpy, reaction Gibbs energy

8. Equilibrium composition for homogeneous systems-reactions in the gas phase.

9. Equilibrium composition for heterogeneous systems (gas-solid phase).

10. Simultaneous chemical equlibrium

11. Adiabatic balance for chemical reaction. Limitation by equilibrium.

Last update: Krýsa Josef (29.06.2018)
Entry requirements -

none

Last update: Sedlářová Ivona (26.06.2018)
Registration requirements -

none

Last update: Sedlářová Ivona (26.06.2018)
Course completion requirements -

Oral exam

Last update: Krýsa Josef (29.06.2018)
 
VŠCHT Praha