SubjectsSubjects(version: 855)
Course, academic year 2019/2020
  
Experimental Techniques in Electrochemistry, Photoelectrochemistry and Photocatalysis - P105011
Title: Experimentální techniky v elektrochemii, fotoelektrochemi a fotokatalýze
Guaranteed by: Department of Inorganic Technology (105)
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: you can enroll for the course in winter and in summer semester
Guarantor: Krýsa Josef prof. Dr. Ing.
Is interchangeable with: AP105011
Annotation -
Last update: Sedlářová Ivona Ing. Ph.D. (02.07.2018)
The aim of the course is the descriptions of the methods used in electrochemistry, photoelectrochemistry and photocatalysis. Emphasis is given not only on the understanding of electrochemical and photoelectrochemical processes, but also on their application primarily in the energetics, analytical chemistry and environmental cleaning. After passing of the graduate gets a comprehensive overview of experimental performance and benefits of electrochemical and photoelectrochemical methods.
Aim of the course -
Last update: Sedlářová Ivona Ing. Ph.D. (02.07.2018)

Students will be able to:

  • use the experimental methods used in electrochemistry, photoelectrochemistry and photocatalysis
  • detect if the studied electrochemical reaction takes place irreversibly
  • select the appropriate electrochemical method for given application in electrochemistry, photoelectrochemistry and photocatalysis

Literature -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

A.J.Bard, L.R. Faulkner: Electrochemical methods, Fundamentals and Applications, Wiley, New York.

Rasi Varna, J. R. Selman: Techniques for characterization of electrodes and electrochemical processes, Willey - Interscience Publication, 1990

Riidiger Memming, Semiconductor Electrochemistry, WILEY-VCH, 2001

Learning resources -
Last update: Krýsa Josef prof. Dr. Ing. (02.07.2018)

https://en.wikipedia.org/wiki/Electrochemistry

https://en.wikipedia.org/wiki/Photochemistry

https://en.wikipedia.org/wiki/Photoelectrochemistry

https://en.wikipedia.org/wiki/Photocatalysis

https://en.wikipedia.org/wiki/Photoelectrochemical_oxidation

https://en.wikipedia.org/wiki/Heterojunction

Teaching methods -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

lectures

Requirements to the exam -
Last update: Sedlářová Ivona Ing. Ph.D. (26.06.2018)

none

Syllabus -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

The subject is focused on the following topics:

1. Faradaic and non-faradaic processes. Electrochemical instrumentation, electro-chemical cell.

2. Charge transport in electrolyte. Faraday's laws, the electrode potential.

3. Kinetics of electrode reactions, charge transfer overpotential, concentration overpotential, limiting current density

4. Techniques based on the potential control, potentiostatic and potentiodynamic methods.

5. Techniques based on the current control.

6. Polarography.

7. Coulometry, bulk electrolysis, stripping voltammetry.

8. Convective method-RDE, RRDE.

9. Electrochemical impedance spectroscopy.

10. Principles of semiconductor physics, optical properties, excitation and recombination,

11. Semiconductor-electrolyte interface, Fermi level, flat band potential, photocurrent measurement.

12. Experimental techniques in photocatalysis

Entry requirements -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

none

Registration requirements -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

none

Course completion requirements -
Last update: Krýsa Josef prof. Dr. Ing. (29.06.2018)

Oral exam

Coursework assessment
Form Significance
Oral examination 100

 
VŠCHT Praha