SubjectsSubjects(version: 855)
Course, academic year 2019/2020
  
Texture Properties of Porous Media (Solids) - P111002
Title: Texturní vlastnosti porézních látek
Guaranteed by: Department of Organic Technology (111)
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 other [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Šolcová Olga Ing. DSc.
Soukup Karel Ing. Ph.D.
Interchangeability : D111005
Is interchangeable with: AP111002
Annotation -
Last update: Pátková Vlasta (19.04.2018)
Subject is focused on issues concerning determination of the porous material texture properties including description of gas transport in porous solids. Basic characterization and description of the porous material texture properties by the physical sorption of inert gases, mercury porosimetry and helium pycnometry belongs to the main topic of this subject. The integral part is also application of theoretical knowledge for evaluation of the real data of porous solids with pores in the range from 0.3 nm to 100 m.
Aim of the course -
Last update: Pátková Vlasta (19.04.2018)

The students will be able to:

1. Know the basic issues and the possibility of the textural properties determination of porous solids.

2. Select and apply the appropriate characterization method to process obtained experimental data obtained and to evaluate the textural properties of any porous material.

3. Znát základní popis transportních jevů v pórech včetně jejich využití pro stanovení transportních parametrů porézních materiálů Know the basic description of transport phenomena in the pores, including their application for determination of the porous materials transport parameters.

Literature -
Last update: Pátková Vlasta (19.04.2018)

S. Lowell, J.E.Shields, M. A. Thomas. M. Thommes:Characterization of Porous Solids and Powders; Surface Area, Pore Size and Density Kluwer Academic Publishers, 2004

Gas Transport in Porous Media. (Ho, C.K. - Webb, S.W., Ed.), Springer, Dordrecht 2006.

F. Rouquerol, J. Rouquerol & K. Sing: Adsorption by Powders & Porous Solids: Principles, Methodology and Applications. Academic Press, GB, Cornwall, Bodmin 1999.

Duong D. Do: Adsorption Analysis: Equilibria and Kinetics. Imperial College Press, London 1998.D:

Learning resources -
Last update: Pátková Vlasta (19.04.2018)

Teacher provides PDF copies of lectures.

Syllabus -
Last update: Pátková Vlasta (19.04.2018)

1. Introduction of the material texture properties theme.

2. Physical adsorption of inert gases and its mechanism.

3. Types of adsorption isotherms, Langmuirova adsorption isotherm.

4. Isotherm BET, SBET.evaluation

5. Microporous sorbents, application of SBET , three parameters BET.

6. Comparative methods (α - plot, t - plot), reference isotherms.

7. DistribucePore-size distribution of mezo- a mikropores, DFT methods.

8. Mercury porozimetry and helium pycnometry.

9. Practical demonstration of methods.

10. Introduction into description of transport phenomena in pores.

11. Graham’s a Wicke-Kallenbach cell, diffusion in pores.

12. Chromatographic method of the diffusion measurement in dynamic regime.

13. Permeation of gases.

14. Practical demonstration of mwethods for the transport parameter evaluation.

Course completion requirements -
Last update: Pátková Vlasta (19.04.2018)

Final oral exam.

Coursework assessment
Form Significance
Oral examination 100

 
VŠCHT Praha