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Subject provides basic information on methods of measurements of selected physico-chemical quantities. Selected quantities (temperature, pressure, volume/density, thermal quantities) are basic quantities needed as input for classical thermodynamics employed for evaluation of non-measurable thermodynamic properties of systems.
Last update: TAJ403 (25.09.2013)
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After passing successfully the subject a student should have an overall knowledge on methods for measurement of temperature, pressure, volume/density, and thermal properties. In practice he/she should be able to select a proper method for a particular conditions and requirements. Last update: Cibulka Ivan (20.08.2013)
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R: Ivan Cibulka,Lubomír Hnědkovský,Vladimír Hynek: Základní fyzikálně-chemické veličiny a jejich měření. E-textbook (http://ufch.vscht.cz/files/uzel/0013864/ZaklaFyzChemVelicin_all_7.pdf) A: Research articles published in the literature cited as sources during the course and in the E-textbook. Last update: Vopička Ondřej (05.02.2018)
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Written test with the result of min. 50 points of 100 naximum. If failed then either the repetition of the test or the oral examination (upon the decision of a teacher). Last update: Cibulka Ivan (20.08.2013)
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1. Temperature scales, their definitions and applications. 2. Definition of thermodynamic temperature and its units. 3. Methods for accurate measurements of temperature and electric resistance. Thermometeres, thermocouples. 4. Concept of pressure. Pressure generation, pressure standards. 5. Measurement of pressure, mechanical and electrical transducers. 6. Vacuum. Vacuum generation, vacuum pumps, measurement of low pressures. 7. Methods for measurements of volumetric properties. Direct PVT methods. 8. Pycnometers, application of methods, examples of PVT devices. 9. Indirect methods (vibrating-tube densimeter, buoyancy methods, speed-of-sound methods). 10.Analysis of effects related to density (temperature, pressure, sample purity). 11.Heat. Measurements of heat effects, calorimetry. 12.Methods of purification of substances. Methods for evaluation of purity of samples. 13.Laboratory excercises. 14.Excursion at the Department of Physical Chemistry (selected experimental techniques). Last update: Cibulka Ivan (20.08.2013)
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E-textbook http://ufch.vscht.cz/files/uzel/0013864/ZaklaFyzChemVelicin_all_7.pdf : Ivan Cibulka,Lubomír Hnědkovský,Vladimír Hynek: Základní fyzikálně-chemické veličiny a jejich měření. Last update: Vopička Ondřej (05.02.2018)
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To study this subject it is necessary either to pass or to be enroled in the subject N403011 (Fyzikální chemie I/Physical Chemistry I) or in the subject N403035 (Fyzikální chemie A/Physical Chemistry A). Last update: Vopička Ondřej (05.02.2018)
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Successfull passing the subjects: General and Inorganic Chemistry I Physics I or Physics A Last update: Vopička Ondřej (05.02.2018)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
Účast na seminářích | 1.5 | 42 | ||
3 / 3 | 84 / 84 |
Coursework assessment | |
Form | Significance |
Examination test | 100 |