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Theoretical fundamentals of the use of chemical reactions for chemical analysis are extended especially with respect to the existence of systematic bias of analytical results. The first part is focused on the correct expression of measurement results. The second part is devoted to chemical equilibria in analytical chemistry (protolytic, complexation, precipitation and redox systems) that affect analyte behaviour in the aqueous environment with emphasize on graphical modeling of equilibrium composition. The last part is devoted to nonlinear regression and various tools for experimental data processing with the aim of equilibrium constants determination in aqueous solutions. In exercises, the students solve individually practical problems using simple algorithms.
Last update: Záruba Kamil (15.02.2018)
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A: Ionic Equilibrium: Solubility and pH Calculations James N. Butler Wiley, 1998 Last update: Pátková Vlasta (05.01.2018)
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Lectures and seminars. Last update: Pátková Vlasta (05.01.2018)
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The students solve five tasks during the semester and they write final test. Last update: Pátková Vlasta (05.01.2018)
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1. Terminology of analytical chemistry and measurement 2. Thermodynamics of protolytic equilibria, pH calculation 3. titration curves, estimation of titration error of acidobasic titration 4. Calculation tools for solving of analytical chemistry problems - examples of solutions using EXCEL and MALPE software 5. Thermodynamic of precipitation equilibria 6. Precipitation equilibria, the common ion effect, DOPE 7. Thermodynamic of complex equilibria 8. COGS algorithm 9. Effect of complex equilibria on precipitation, DOPE 10. Thermodynamics of redox equilibria 11. Equilibria in binary systems, kinetic methods of analysis 12. Nonlinear regression 13. Determination of thermodynamic constants (aqueous solutions) 14. Exam test Last update: Záruba Kamil (15.02.2018)
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Excel sheets prepared and solved in seminars Last update: Pátková Vlasta (05.01.2018)
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Students will be able to
Characterize protolytic, complexometric, precipitation and redox equilibria and their inffluence on an analytical determination in aqueous environment;
Construct and interprete distribution diagrams and predominance array diagrams;
Process measured data with nonlinear regression. Last update: Záruba Kamil (15.02.2018)
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Analytical Chemistry I. Last update: Pátková Vlasta (05.01.2018)
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Analytical Chemistry I. Last update: Pátková Vlasta (05.01.2018)
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| Teaching methods | ||||
| Activity | Credits | Hours | ||
| Účast na přednáškách | 1 | 28 | ||
| Práce na individuálním projektu | 1 | 28 | ||
| Příprava na zkoušku a její absolvování | 1 | 28 | ||
| Účast na seminářích | 1 | 28 | ||
| 4 / 4 | 112 / 112 | |||
| Coursework assessment | |
| Form | Significance |
| Report from individual projects | 33 |
| Examination test | 67 |