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The main objective of the course is to deepen the knowledge of macromolecular chemistry and further to extend this knowledge by new findings in the field: basic terms, polymer nomenclature, molecular structure of polymers, general principles and classification of polyreactions, polymerizability-thermodynamics of polymerization, radical polymerizations, ionic processes, anionic polymerization, cationic polymerization, coordination polymerization, polycondensation and polyaddition. Block copolymers, optically active polymers, liquid crystalline polymers, special polyinsertion processes, polymerization of cyclic monomers, cyclic oligomers, living polymerizations, macromonomers. Lectures are designed to give the specific knowledge to broader theoretical and also technological context.
Last update: Pátková Vlasta (18.04.2018)
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Attending of seminars, oral exam. Last update: Pátková Vlasta (18.04.2018)
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R: Elias H.G.: Macromolecules, Vol.1: Chemical Structures and Synthesis, Wiley-VCH GmbH & Co, Weinheim 2005, ISBN-10: 3-527-31172-6 R: Elias H.G.: Macromolecules, Vol.2: Industrial Polymer and Synthesis, Wiley-VCH GmbH & Co, Weinheim 2007, ISBN-978-3-527-31173-6 R: Chanda M.: Introduction to Polymer Science and Chemistry, A Problem Solving Approach, CRC Taylor &Francis 2006, ISBN-0-8493-7384-0 (978-8493-7384-8) R: Timothy P. Lodge, Paul C. Hiemenz, Polymer Chemistry , 3rd Edition, Taylor & Francis Ltd, 2021 ISBN 9781466581647 A: Encyclopedia Polymer Science and Technology, 4th Edition, online ISBN: 978-0-471-44026-4, Wiley - on line Library A: Matyjaszewski K., Gnanu Y., Leibler L. (Eds.), Macromelecular Engineering, Wiley - VC Verlag, Weinheim 2007, ISBN 978-3-527-31446-1 , Vol 1.: Synthetic Techniques, Vol 2.: Elements of Macro Molecular Structural Control, l Vol 3.: Structure-Properties Correlation Using Modern Characterisation Techniques Vol 4.: Application A: Matyjaszewski K., Moeller M. (Eds.), Polymer Science: A Comprehensive Reference, Elsevier B.V. 2012, in ten volumes, ISBN 978-0-08-087862-1 Last update: Merna Jan (04.05.2022)
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1. Basic definitions, classification of polymerization mechanisms and polymer nomenclature based on the newest IUPAC recommendations 2. Structure vs. properties of polymers 3. Polymerizability of chemical compounds, thermodynamics of polymerization, polymerization equilibria 4. Radical (co)polymerization processes 5. Ionic (co)polymerization processes, photopolymerization 6. Polymerization of cyclic monomers, cyclic oligomers 7. Coordination polymerization, catalysts, stereoregularity, metathesis 8. Polycondensation and polyaddition 9. Kinetics of polymerization 10. Living and controlled polymerization processes (ionic, NMR, ATRP, RAFT, OMRP), stratégy for synthesis of complex polymers (block and grafted copolymers, star polymers), click reactions 11. Preparation and properties of block copolymers, self-assembly of polymers 12. Self-healing polymers, vitrimers 13. Sequence defined polymers, stimuli-responsive polymers 14. Optically active polymers, stereoselective synthesis, liquid crystalline polymers
Last update: Merna Jan (03.05.2022)
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Student will be able to: Utilize detailed knowledge of mechanisms and kinetics of the polymerization processes to its critical analysis Design the polymerization experiments based on obtained knowledge of polyreactions mechanism Understand and describe causal link between physical and chemical aspects of polymer synthesis and applications Last update: Pátková Vlasta (18.04.2018)
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