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The aim of this course is to acquire knowledge about mechanism of organic reactions based on the analysis of structural and electronic factors present in reactants and products.
Last update: BOHM (24.04.2014)
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It is compulsory to pass written examination test with the result at least 50%, and finally to pass successfuly the oral examination. Last update: Cibulka Radek (10.05.2014)
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R: Böhm S. : Fyzikální organická chemie, CD verze učebního textu A: Eric V. Anslyn, Dennis A. Dougherty : Modern Physical Organic Chemistry 2004. ISBN 1891389319.
Last update: Cibulka Radek (04.09.2015)
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1. Structure and mechanism
2. Kinetic studies
3. Linear Gibbs energy relations
4. Acids and bases
5. The reaction medium
6. MO theory
7. Aliphatic nucleophilic substitution
8. Elimination reactions
9. Addition to C=C double bonds
10.Aromatic electrophilic substitution
11.Addition to C=O group and related reactions
12.The hydrolysis of carboxylic esters
13.Aromatic nucleophilic substitution
14.Molecular rearrangements
15.Aliphatic radical substitution
16.Pericyclic reactions Last update: BOHM (24.04.2014)
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Lectures on CD Last update: BOHM (24.04.2014)
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Students will be able to :
understand basic concept of physical organic chemistry
use of various methods of study of reaction mechanisms
understand reaction mechanisms of common chemical reactions
elucidate the relations between structure and reactivity of organic compounds Last update: BOHM (24.04.2014)
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Organic Chemistry I + II
Physical Chemistry I + II Last update: BOHM (24.04.2014)
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Coursework assessment | |
Form | Significance |
Oral examination | 100 |