SubjectsSubjects(version: 948)
Course, academic year 2021/2022
  
Physical Organic Chemistry - AM110016
Title: Physical Organic Chemistry
Guaranteed by: Department of Organic Chemistry (110)
Faculty: Faculty of Chemical Technology
Actual: from 2020 to 2022
Semester: summer
Points: summer s.:5
E-Credits: summer s.:5
Examination process: summer s.:
Hours per week, examination: summer s.:2/2, C+Ex [HT]
Capacity: unlimited / unlimited (unknown)
Min. number of students: unlimited
Language: English
Teaching methods: full-time
Teaching methods: full-time
Level:  
For type: Master's (post-Bachelor)
Note: course can be enrolled in outside the study plan
enabled for web enrollment
Guarantor: Krupička Martin Ing. Ph.D.
Interchangeability : N110007
Annotation -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)
The aim of this course is to acquire knowledge about mechanism of organic reactions based on the analysis of structural and electronic factors present in reactants and products.
Aim of the course -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

Students will be able to :

understand basic concept of physical organic chemistry

use of various methods of study of reaction mechanisms

understand reaction mechanisms of common chemical reactions

elucidate the relations between structure and reactivity of organic compounds

Literature -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

A: Eric V. Anslyn, Dennis A. Dougherty : Modern Physical Organic Chemistry. 1891389319

Learning resources -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

Lectures on CD

Syllabus -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

1. Structure and mechanism

2. Kinetic studies

3. Linear Gibbs energy relations

4. Acids and bases

5. The reaction medium

6. MO theory

7. Aliphatic nucleophilic substitution

8. Elimination reactions

9. Addition to C=C double bonds

10.Aromatic electrophilic substitution

11.Addition to C=O group and related reactions

12.The hydrolysis of carboxylic esters

13.Aromatic nucleophilic substitution

14.Molecular rearrangements

15.Aliphatic radical substitution

16.Pericyclic reactions

Registration requirements -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

No.

Course completion requirements -
Last update: Krupička Martin Ing. Ph.D. (18.12.2023)

The examination has written and oral part.

 
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