Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
The course deals with the state behavior and thermodynamic properties of homogeneous fluid systems. Special attention is devoted to the description of state behavior of multicomponent systems, as well as to the calculation of thermodynamic properties of such systems. Calculation and usage of partial molar quantities is also covered. Finally, phase equilibria calculations by means of EOS (equations of state) are discussed.
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
The course deals with the state behavior and thermodynamic properties of homogeneous fluid systems. Special attention is devoted to the description of state behavior of multicomponent systems, as well as to the calculation of thermodynamic properties of such systems. Calculation and usage of partial molar quantities is also covered. Finally, phase equilibria calculations by means of EOS (equations of state) are discussed.
Výstupy studia předmětu -
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
Students will be able to:
1) evaluate the state of the system (temperature, pressure, volume, mole number) by means of simple EOS (virial, cubic) as well as by means of complex, Wagner-type EOS.
2) evaluate the same properties for mixtures by using different approaches (mixing rules, corresponding state principle, empirical "laws")
3) calculate heat and work for given conditions (adiabatic, isothermal, isochoric, isobaric).
4) calulate thermodynamic quantities for pure components as well as for mixtures (entropy, enthalpy, Gibbs energy,...) as function of temperature and pressure or temperature and density, respectively.
5) calculate phase equilibria in single- as well as multicomponent mixtures by means of equations of state.
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
Students will be able to:
1) evaluate the state of the system (temperature, pressure, volume, mole number) by means of simple EOS (virial, cubic) as well as by means of complex, Wagner-type EOS.
2) evaluate the same properties for mixtures by using different approaches (mixing rules, corresponding state principle, empirical "laws")
3) calculate heat and work for given conditions (adiabatic, isothermal, isochoric, isobaric).
4) calulate thermodynamic quantities for pure components as well as for mixtures (entropy, enthalpy, Gibbs energy,...) as function of temperature and pressure or temperature and density, respectively.
5) calculate phase equilibria in single- as well as multicomponent mixtures by means of equations of state.
Literatura -
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
R: Novák J.P., Růžička K., Fulem M., Calculation of Thermodynamic Functions from Volumetric Properties, doi:10.1039/9781782627043-00476 (Chapter 17 in Volume Properties: Liquids, Solutions and Vapours, Letcher T., Wilhelm E., 2015, Royal Society of Chemistry, London, ISBN: 978-1-84973-899-6)
R: Sandler, S.I., Chemical, biochemical, and engineering thermodynamics. 2006, Hoboken, N.J.: John Wiley. ISBN 978-0-471-66174-0
A: Michelsen, M.L. and J.M. Mollerup, Thermodynamic models : fundamentals & computational aspects. 2007, Holte, Denmark: Tie-Line Publications. ISBN 87-989961-3-4
A: Riazi, M.R., Characterization and properties of petroleum fractions. 2005, West Conshohocken, PA: ASTM International. ISBN 407.0-8031-3361-8
A: Span, R., Multiparameter equations of state : an accurate source of thermodynamic property data. 2000, Berlin: Springer. ISBN 3-540-67311-3
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)
R: Novák J.P., Růžička K., Fulem M., Calculation of Thermodynamic Functions from Volumetric Properties, doi:10.1039/9781782627043-00476 (Chapter 17 in Volume Properties: Liquids, Solutions and Vapours, Letcher T., Wilhelm E., 2015, Royal Society of Chemistry, London, ISBN: 978-1-84973-899-6)
R: Sandler, S.I., Chemical, biochemical, and engineering thermodynamics. 2006, Hoboken, N.J.: John Wiley. ISBN 978-0-471-66174-0
A: Michelsen, M.L. and J.M. Mollerup, Thermodynamic models : fundamentals & computational aspects. 2007, Holte, Denmark: Tie-Line Publications. ISBN 87-989961-3-4
A: Riazi, M.R., Characterization and properties of petroleum fractions. 2005, West Conshohocken, PA: ASTM International. ISBN 407.0-8031-3361-8
A: Span, R., Multiparameter equations of state : an accurate source of thermodynamic property data. 2000, Berlin: Springer. ISBN 3-540-67311-3
Studijní opory -
Poslední úprava: Kopecká Blanka Ing. Ph.D. (03.08.2018)