SubjectsSubjects(version: 955)
Course, academic year 2023/2024
Physical Chemistry II - AB403004
Title: Physical Chemistry II
Guaranteed by: Department of Physical Chemistry (403)
Faculty: Faculty of Chemical Engineering
Actual: from 2021
Semester: summer
Points: summer s.:6
E-Credits: summer s.:6
Examination process: summer s.:
Hours per week, examination: summer s.:3/2, C+Ex [HT]
Capacity: unlimited / unlimited (unknown)
Min. number of students: unlimited
State of the course: taught
Language: English
Teaching methods: full-time
Teaching methods: full-time
Note: you can enroll for the course repeatedly
course can be enrolled in outside the study plan
enabled for web enrollment
Guarantor: Růžička Květoslav prof. Ing. CSc.
Řehák Karel doc. Ing. CSc.
Class: Předměty pro fyzikální chemii
Interchangeability : B403004, N403014, N403016, N403040
Is interchangeable with: B403004
This subject contains the following additional online materials
Annotation -
The course deals with selected chapters of physical chemistry on advanced level. Knowledge acquired in the basic course Physical Chemistry I is extended to real-behaving systems. Subjects covered involve state behavior of matter, thermodynamics of fluids, phase and chemical equilibria, properties of electrolyte-containing systems, chemical kinetics, and basic concepts of surface chemistry.
Last update: Kubová Petra (06.03.2019)
Aim of the course -

Students will be able to:

  • explain and describe basic relations governing physico-chemical processes
  • solve real physico-chemical problems encountered in chemical engineering practice

Last update: Kubová Petra (06.03.2019)
Literature -

R: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373

R: Malijevský A., Physical Chemistry in Brief, Institute of Chemical-technology, 2005. PDF document will be available by the E-learning portal.

Last update: Řehák Karel (14.08.2019)
Learning resources -

Basic information and learning resources: See E-learning

Other literature and learning applications:

Last update: Kubová Petra (06.03.2019)
Teaching methods -

Combination of lectures and seminar meetings.

Last update: Kubová Petra (06.03.2019)
Requirements to the exam -

For participation in the exam each student has to get the credit from the seminar meetings. A student will be granted the credit when he/she gains the average 50 per cent of the maximum available from the written tests (partial tests during the semester or the summary test).

Last update: Kubová Petra (06.03.2019)
Syllabus -

1. Molecular approach to physical chemistry.

2. Equations of state for real fluids, theorem of corresponding states.

3. Energetics of chemical reactions, enthalpy balance.

4. Implications of I. and II. Laws of thermodynamics, temperature and presseure dependences of state functions.

5. Thermodynamics of irreversible processes, heat engines, liquefacation of gases.

6. Thermodynamics of solutions, fugacity, activity.

7. Phase equilibia in real systems.

8. Spontaneous chemical change and Gibbs energy, chemical equilibrium in systems of various types.

9. Theory of electrolytic dissociation, equilibria in electrolyte solutions.

10.Difusion, migration of ions in electric field, conductivity, Kohlrausch law.

11.Reversible galvanic cells, types of electrodes, galvanic cells as power sources.

12.Kinetics of simultaneous reactions, kinetics and chemical equilibrium.

13.Reaction mechanisms; photochemical,radical, and catalyzed reactions.

14.Introduction to surface chemistry.

Last update: Kubová Petra (06.03.2019)
Entry requirements -

Fyzikální chemie I, Matematika A, Matematika B, Fyzika I

Last update: Kubová Petra (06.03.2019)
Registration requirements -

Fyzikální chemie I, Matematika A, Matematika B

Last update: Kubová Petra (06.03.2019)
Course completion requirements -

Acquiring credit (meeting the minimum requirements of the computational part)

The exam (comutational test + oral exam)

Last update: Kubová Petra (06.03.2019)