SubjectsSubjects(version: 947)
Course, academic year 2023/2024
Theoretical Fundamentals of Analytical Chemistry - D402033
Title: Teoretické základy analytické chemie
Guaranteed by: Department of Analytical Chemistry (402)
Faculty: Faculty of Chemical Engineering
Actual: from 2011
Semester: winter
Points: winter s.:0
E-Credits: winter s.:0
Examination process: winter s.:
Hours per week, examination: winter s.:0/0, other [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
For type:  
Note: course is intended for doctoral students only
can be fulfilled in the future
Guarantor: Záruba Kamil doc. Ing. Ph.D.
Annotation -
Last update: VED402 (25.09.2013)
Theoretical fundamentals of the use of chemical reactions for chemical analysis are extended especially with respect to existence of systematic bias of analytical results. First part is focused on proper expression of measurement results. Second part is devoted to chemical equilibria in analytical chemistry (protolytic, complexometric, precipitation and redox systems) that affect analyte behaviour in aueous environment. The last part deepens knowledge of optimalization and calibration aspects in analytical chemistry. In excersizes, the students sovle individually practical problems using simple algorithms.
Aim of the course -
Last update: VED402 (25.09.2013)

Students will be able to

Characterize protolytic, complexometric, precipitation and redox equilibria and their inffluence on an analytical determination in aqueous environment;

Construct and interprete distribution diagrams and predominance array diagrams;

Estimate competently key factors of analytical method optimalization.

Literature -
Last update: VED402 (25.09.2013)

D: Ionic Equilibrium: Solubility and pH Calculations James N. Butler, Wiley, 1998, ISBN 0-471-58526-2

Studijní opory - angličtina

Learning resources -
Last update: VED402 (25.09.2013)

Excel sheets prepared and solved in seminars

Teaching methods -
Last update: VED402 (25.09.2013)

Lectures and seminars (work on individual assignments)

Syllabus -
Last update: VED402 (25.09.2013)

1. Terminology of analytical chemistry and measurement, combined uncertainty.

2. Protolytic equalibria: Thermodynamics

3. Protolytic equalibria: Titration error

4. Precipitation equilibria: Thermodynamics

5. Precipitation equilibria: The common ion effect, DOPE

6. Complex eqilibria: Thermodynamics

7. Complex eqilibria: COGS algorithm

8. Effect of complex equilibria on precipitation, DOPE

9. Redox equlibria: Thermodynamics

10. Equilibria in binary systems, kinetic methods of analysis

11. Calibration in analytical chemistry

12. Nonlinear regression

13. Optimalization in analytical chemistry

14. Exam

Registration requirements -
Last update: VED402 (25.09.2013)

Analytical chemistry I.

Teaching methods
Activity Credits Hours
Obhajoba individuálního projektu 0.5 14
Účast na přednáškách 1 28
Práce na individuálním projektu 0.5 14
Příprava na zkoušku a její absolvování 1 28
Účast na seminářích 1 28
4 / 0 112 / 0
Coursework assessment
Form Significance
Report from individual projects 100