SubjectsSubjects(version: 877)
Course, academic year 2020/2021
  
Chemical Thermodynamics - M403018
Title: Chemická termodynamika
Guaranteed by: Department of Physical Chemistry (403)
Actual: from 2019
Semester: winter
Points: winter s.:5
E-Credits: winter s.:5
Examination process: winter s.:
Hours per week, examination: winter s.:2/2 C+Ex [hours/week]
Capacity: unlimited / unlimited (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: Master's (post-Bachelor)
Note: course can be enrolled in outside the study plan
enabled for web enrollment
Guarantor: Řehák Karel doc. Ing. CSc.
Interchangeability : AM403018
Z//Is interchangeable with: AM403018
This subject contains the following additional online materials
Annotation -
Last update: Řehák Karel doc. Ing. CSc. (25.06.2020)
The course is focused on basic chemical-engineering calculations. Utilizations of equations of state and thermodynamic models which are implemented in chemical-engineering simulators are demonstrated. Theory background for calculations and basic equations are given in lectures. Computational skills are taught with the help of the Maple software.
Aim of the course -
Last update: Řehák Karel doc. Ing. CSc. (07.02.2018)

Students will be able to:

  • calculate state behaviour of real fluids and mixtures
  • calculate phase equilibria in two-component systems (considering real behaviour)
  • solve chemical equilibrium in simplified systems

(all calculations performed in the Maple software or Wolfram Mathematica)

Literature -
Last update: Řehák Karel doc. Ing. CSc. (07.02.2018)

R: J.M. Prausnitz, R.N. Lichtenthaler, E.G. Azevedo, Molecular thermodynamics of fluid-phase equilibria, Prentice-Hall PTR, 1999. 9780139777455

R: Novák J. a kol., Fyzikální chemie - bakalářský a magisterský kurz, VŠCHT, Praha 2008, 9788070806753

R: Novák J., Růžička K., Chemická termodynamika I, Stavové chování a termodynamické vlastnosti reálných tekutin, Vysoká škola chemicko-technologická, Praha 2002, 8070805013

R: Dohnal V., Novák J., Matouš J.: Chemická termodynamika II, Vysoká škola chemicko-technologická, Praha 1996, 8070802758

A: Riazi M.R., Characterization And Properties Of Petroleum Fractions, ASTM International, 2005, Philadelphia, 2005, 0803133618

A: Růžička V., Odhadové metody pro fyzikálně-chemické vlastnosti tekutin, Vysoká škola chemicko-technologická, Praha 1996, 8070802561

Learning resources -
Last update: Řehák Karel doc. Ing. CSc. (07.02.2018)

Basic information and learning resources: See the E-learning

Other literature and learning applications:

https://ufch.vscht.cz/studium/literatura

https://ufch.vscht.cz/studium/elektronicke_pomucky

Syllabus -
Last update: Řehák Karel doc. Ing. CSc. (07.02.2018)

1. State behaviour of real mixtures of pure fluids, critical quantities and their prediction

2. Equations of state of real fluids, theorem of corresponding states

3. State behaviour of real mixtures

4. Virial equation of state, prediction of virial coefficients.

5. Thermodynamic properties of fluids, calculation of heat and work in typical processes.

6. Residual molar quantities and their applications.

7. Thermodynamic properties of components in mixtures. Excess quantities.

8. Activity and activity coefficients. Thermodynamic models for excess Gibbs energy

9. Vapour-liquid equilibria at low and high pressures, determination and prediction.

10. Solubility of gases in liquids

11. Liquid-liquid equilibria

12. Liquid-solid equilibria

13. Chemical equilibrium of simple systems.

14. Chemical equilibrium of complex systems.

Registration requirements -
Last update: Řehák Karel doc. Ing. CSc. (07.02.2018)

Matematika A,B

Fyzikální chemie I, nebo Fyzikální chemie A,B

Course completion requirements -
Last update: Řehák Karel doc. Ing. CSc. (02.03.2018)

Acquiring credit (meeting the minimum requirements of the computational part)

The exam test

Teaching methods
Activity Credits Hours
Účast na přednáškách 1 28
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1 28
Příprava na zkoušku a její absolvování 2 56
Účast na seminářích 1 28
5 / 5 140 / 140
 
VŠCHT Praha