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The course is meant for students who do not intend to continue in the master study.
The subject extends chemical thermodynamics from the Physical chemistry I course to real behaviour. All calculations are preformed with the simplest models of real behaviour.
Last update: Cibulka Ivan (20.08.2013)
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Students will be able to: perform simple calculations of state behaviour of real fluids, thermochemistry, phase and chemical equilibria; understand the thermodynamic principles of heat engines; understand the use of thermodynamic models for activity coefficients and state behaviour. Last update: TAJ403 (13.12.2013)
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R: Novák J. a kol., Fyzikální chemie - bakalářský a magisterský kurz, VŠCHT, Praha 2008, 9788070806753 R: Novák J. a kol., Příklady a úlohy z fyzikální chemie I, VŠCHT Praha, 2000, 8070803940 A: A. Malijevský, et. al: Physical chemistry in brief. Institute of Chemical Technology, Prague, 2005. (www.vscht.cz/fch/en/tools/breviary.html) A: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 Last update: TAJ403 (25.08.2013)
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Passing through either two current tests or one summary test with minimum average of 50 points of max. 100 point to be allowed for the examination. Examination: written test containing theoretical part (questions) and solving numerical problems. Last update: Cibulka Ivan (20.08.2013)
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1. Thermodynamic systems, variables, units, description of states, composition. 2. State behaviour of real fluids. 3. State behaviour of real fluid mixtures. 4. Changes of energy, work and heat. Internal energy an enthalpy. 5. Thermochemistry. Enthalpic balance. 6. Thermodynamic laws and their implications. Calculation of thermodynamic quantities. 7. Thermodynamics of mixtures, fugacity, activity. 8. Spontaneous chemical reaction. Chemical equilibrium. 9. Response of equilibria to the conditions. 10.Equilibria in electrolyte solutions. 11.Gibbs phase rule. Phase equilibrium in one-component systems. 12.Vapour-liquid equilibrium, solubility of gases in liquids. 13.Liquid-liquid equilibrium. 14.Solid-liquid equilibrium. Last update: TAJ403 (25.09.2013)
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http://www.vscht.cz/fch/cz/pomucky/ZCHT.pdf http://www.vscht.cz/fch/cz/vyuka/N403003.html Last update: Cibulka Ivan (20.08.2013)
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Succesfull passing the subjects General Chemistry, Physics I Physical Chemistry I Last update: Cibulka Ivan (20.08.2013)
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Physical Chemistry I (Fyzikální chemie I) Last update: Cibulka Ivan (20.08.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1 | 28 | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
Účast na seminářích | 0.5 | 14 | ||
4 / 4 | 112 / 112 |
Coursework assessment | |
Form | Significance |
Examination test | 50 |
Continuous assessment of study performance and course -credit tests | 50 |