SubjectsSubjects(version: 902)
Course, academic year 2022/2023
  
Macromolecular Chemistry - P112002
Title: Makromolekulární chemie
Guaranteed by: Department of Polymers (112)
Actual: from 2022
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0 [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Merna Jan prof. Ing. Ph.D.
Interchangeability : D112002
Is interchangeable with: AP112002
Annotation -
Last update: Pátková Vlasta (18.04.2018)
The main objective of the course is to deepen the knowledge of macromolecular chemistry and further to extend this knowledge by new findings in the field: basic terms, polymer nomenclature, molecular structure of polymers, general principles and classification of polyreactions, polymerizability-thermodynamics of polymerization, radical polymerizations, ionic processes, anionic polymerization, cationic polymerization, coordination polymerization, polycondensation and polyaddition. Block copolymers, optically active polymers, liquid crystalline polymers, special polyinsertion processes, polymerization of cyclic monomers, cyclic oligomers, living polymerizations, macromonomers. Lectures are designed to give the specific knowledge to broader theoretical and also technological context.
Aim of the course -
Last update: Pátková Vlasta (18.04.2018)

Student will be able to:

Utilize detailed knowledge of mechanisms and kinetics of the polymerization processes to its critical analysis

Design the polymerization experiments based on obtained knowledge of polyreactions mechanism

Understand and describe causal link between physical and chemical aspects of polymer synthesis and applications

Literature -
Last update: Merna Jan prof. Ing. Ph.D. (04.05.2022)

R: Elias H.G.: Macromolecules, Vol.1: Chemical Structures and Synthesis, Wiley-VCH GmbH & Co, Weinheim 2005, ISBN-10: 3-527-31172-6

R: Elias H.G.: Macromolecules, Vol.2: Industrial Polymer and Synthesis, Wiley-VCH GmbH & Co, Weinheim 2007, ISBN-978-3-527-31173-6

R: Chanda M.: Introduction to Polymer Science and Chemistry, A Problem Solving Approach, CRC Taylor &Francis 2006, ISBN-0-8493-7384-0 (978-8493-7384-8)

R: Timothy P. Lodge, Paul C. Hiemenz, Polymer Chemistry , 3rd Edition, Taylor & Francis Ltd, 2021 ISBN 9781466581647

A: Encyclopedia Polymer Science and Technology, 4th Edition, online ISBN: 978-0-471-44026-4, Wiley - on line Library

A: Matyjaszewski K., Gnanu Y., Leibler L. (Eds.), Macromelecular Engineering, Wiley - VC Verlag, Weinheim 2007, ISBN 978-3-527-31446-1 , Vol 1.: Synthetic Techniques, Vol 2.: Elements of Macro Molecular Structural Control, l Vol 3.: Structure-Properties Correlation Using Modern Characterisation Techniques Vol 4.: Application

A: Matyjaszewski K., Moeller M. (Eds.), Polymer Science: A Comprehensive Reference, Elsevier B.V. 2012, in ten volumes, ISBN 978-0-08-087862-1

Syllabus -
Last update: Merna Jan prof. Ing. Ph.D. (03.05.2022)

1. Basic definitions, classification of polymerization mechanisms and polymer nomenclature based on the newest IUPAC recommendations

2. Structure vs. properties of polymers

3. Polymerizability of chemical compounds, thermodynamics of polymerization, polymerization equilibria

4. Radical (co)polymerization processes

5. Ionic (co)polymerization processes, photopolymerization

6. Polymerization of cyclic monomers, cyclic oligomers

7. Coordination polymerization, catalysts, stereoregularity, metathesis

8. Polycondensation and polyaddition

9. Kinetics of polymerization

10. Living and controlled polymerization processes (ionic, NMR, ATRP, RAFT, OMRP), stratégy for synthesis of complex polymers (block and grafted copolymers, star polymers), click reactions

11. Preparation and properties of block copolymers, self-assembly of polymers

12. Self-healing polymers, vitrimers

13. Sequence defined polymers, stimuli-responsive polymers

14. Optically active polymers, stereoselective synthesis, liquid crystalline polymers

Course completion requirements -
Last update: Pátková Vlasta (18.04.2018)

Attending of seminars, oral exam.

 
VŠCHT Praha