SubjectsSubjects(version: 853)
Course, academic year 2019/2020
  
High Resolution Spectroscopy - P402016
Title: Vysocerozlišená spektroskopie
Guaranteed by: Department of Analytical Chemistry (402)
Actual: from 2019
Semester: winter
Points: winter s.:0
E-Credits: winter s.:0
Examination process: winter s.:
Hours per week, examination: winter s.:2/1 other [hours/week]
Capacity: unlimited / unlimited (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type: doctoral
Guarantor: Urban Štěpán prof. RNDr. CSc.
Kania Patrik Ing. Ph.D.
Koucký Jan Ing. Ph.D.
Is interchangeable with: AP402016
Annotation -
Last update: Záruba Kamil doc. Ing. Ph.D. (14.09.2018)
The course focuses on advanced methods of infrared, THz and MW spectroscopies, which will be taught with a common theoretical background. At the same time, advanced experimental methods will be discussed to distinguish high-resolution spectroscopy from other spectroscopies. Simultaneously with the theoretical interpretation, practical demonstrations in specialized laboratories of the Institute of Chemical Technology and of the Academy of Sciences of the Czech Republic will take place.
Literature -
Last update: Záruba Kamil doc. Ing. Ph.D. (17.10.2018)

A: W. Gordy, R.L. Cook, Microwave Molecular Spectra, John Wiley and Sons, New York, 1976

A: H. Kroto, Molecular Rotation Spectra, John Wiley and Sons, New York, 1992

A: M. Hollas, High Resolution Spectroscopy (2nd Ed.), John Wiley and Sons, Chichester, 1998

Syllabus -
Last update: Záruba Kamil doc. Ing. Ph.D. (14.09.2018)

1) Introduction, basic concepts, spectroscopy types according to the quantum mechanical model and energy range, quantum states, Einstein theory of spectral transitions.

2) State populations, radiation transition equation and its special cases.

3) Spectral lines width, causes of spectral line width expansion, resolution of lines

4) Molecular Hamiltonian, Born-Oppenheimer approximation, quantum chemistry and electron spectra, rotational and vibrational Hamiltonian. Rotational, rovibrational,a nd rovibronic spectra.

5) Fine and hyperfine structure of quantum states. Quadrupole splitting. Hyperfine magnetic nuclear spin-orbital interactions. Magnetic nuclear spin-spin interactions, spin statistical weights of levels, Pauli's Principle.

6) Rotational spectroscopy, Hamiltonian, special cases, selection rules. Symmetric tops. Practical examples.

7) Asymmetric tops. Hyper-rotary transitions. Determination of molecular geometry. Decimetric spectroscopy. Practical examples.

8) Vibration-rotation Hamiltonian and spectra. Selection rules for rotation-vibration transitions. Hyperfine structure of rotation-vibration transitions.

9) Vibronic spectra.

10) Doppler limited spectroscopy and sub-Doppler spectroscopy. High and ultra-high resolution. Lamb dip and molecular beams.

11) Planck and monochromatic sources of radiation, lasers.

12) Tunable monochromatic sources of radiation, laser diodes, clystrones, carcinotrones, Schottky diodes. Duplication and other multiplication of photon energy.

13-14) Application of high resolution spectroscopy.

Registration requirements -
Last update: Záruba Kamil doc. Ing. Ph.D. (14.09.2018)

Subject that should be preceded by:

Molecular Spectroscopy and / or Molecular Physical Chemistry and Symmetry.

Quantum chemistry

and some courses of Physics and Mathematics

Course completion requirements -
Last update: Záruba Kamil doc. Ing. Ph.D. (17.10.2018)

Exam.

Coursework assessment
Form Significance
Oral examination 100

 
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