Students will be able to:

1) evaluate the state of the system (temperature, pressure, volume, mole number) by means of simple EOS (virial, cubic) as well as by means of complex, Wagner-type EOS.

2) evaluate the same properties for mixtures by using different approaches (mixing rules, corresponding state principle, empirical "laws")

3) calculate heat and work for given conditions (adiabatic, isothermal, isochoric, isobaric).

4) calulate thermodynamic quantities for pure components as well as for mixtures (entropy, enthalpy, Gibbs energy,...) as function of temperature and pressure or temperature and density, respectively.

5) calculate phase equilibria in single- as well as multicomponent mixtures by means of equations of state.

Students will be able to:

1) evaluate the state of the system (temperature, pressure, volume, mole number) by means of simple EOS (virial, cubic) as well as by means of complex, Wagner-type EOS.

2) evaluate the same properties for mixtures by using different approaches (mixing rules, corresponding state principle, empirical "laws")

3) calculate heat and work for given conditions (adiabatic, isothermal, isochoric, isobaric).

4) calulate thermodynamic quantities for pure components as well as for mixtures (entropy, enthalpy, Gibbs energy,...) as function of temperature and pressure or temperature and density, respectively.

5) calculate phase equilibria in single- as well as multicomponent mixtures by means of equations of state.

R: Novák J.P., Růžička K., Fulem M., Calculation of Thermodynamic Functions from Volumetric Properties, doi:10.1039/9781782627043-00476 (Chapter 17 in Volume Properties: Liquids, Solutions and Vapours, Letcher T., Wilhelm E., 2015, Royal Society of Chemistry, London, ISBN: 978-1-84973-899-6)

R: Sandler, S.I., Chemical, biochemical, and engineering thermodynamics. 2006, Hoboken, N.J.: John Wiley. ISBN 978-0-471-66174-0

A: Michelsen, M.L. and J.M. Mollerup, Thermodynamic models : fundamentals & computational aspects. 2007, Holte, Denmark: Tie-Line Publications. ISBN 87-989961-3-4

A: Riazi, M.R., Characterization and properties of petroleum fractions. 2005, West Conshohocken, PA: ASTM International. ISBN 407.0-8031-3361-8

A: Span, R., Multiparameter equations of state : an accurate source of thermodynamic property data. 2000, Berlin: Springer. ISBN 3-540-67311-3

R: Novák J.P., Růžička K., Fulem M., Calculation of Thermodynamic Functions from Volumetric Properties, doi:10.1039/9781782627043-00476 (Chapter 17 in Volume Properties: Liquids, Solutions and Vapours, Letcher T., Wilhelm E., 2015, Royal Society of Chemistry, London, ISBN: 978-1-84973-899-6)

R: Sandler, S.I., Chemical, biochemical, and engineering thermodynamics. 2006, Hoboken, N.J.: John Wiley. ISBN 978-0-471-66174-0

A: Michelsen, M.L. and J.M. Mollerup, Thermodynamic models : fundamentals & computational aspects. 2007, Holte, Denmark: Tie-Line Publications. ISBN 87-989961-3-4

A: Riazi, M.R., Characterization and properties of petroleum fractions. 2005, West Conshohocken, PA: ASTM International. ISBN 407.0-8031-3361-8

A: Span, R., Multiparameter equations of state : an accurate source of thermodynamic property data. 2000, Berlin: Springer. ISBN 3-540-67311-3

1. Fundamentals of chemical thermodynamics.

2. Thermodynamic properties of ideal gas mixtures. Critical point.

3. Intermolecular interactions. Virial equation of state.

4. Cubic and fundamental equations of state for real fluids.

5. Theorem of corresponding states and its application.

6. State bahaviour of real mixtures.

7. Departure and residual properties of ral fluids, Q quantities.

8. Thermodynamic properties of real fluids.

9. Calculation of heat and work at different conditions.

10. Partial molar properties.

11. Fugacity and chemical potential.

12. Phase equilibria of single component systems.

13. Solving mixture phase equilibria by equations of state.

14. Phase stability (splitting of homogeneous system into two phases).

1. PVT behaviour of real fluids.

2. Introduction to intermolecular forces, Lennard - Jones potential.

3. Virial equation of state.

4. Equations of state for real fluids.

5. Theorem of corresponding states and its application.

6. State bahaviour of real mixtures.

7. Thermodynamic properties of ideal gas.

8. Departure function of real gas.

9. Termodynamic properties of real fluids.

10. Calculation of heat and work at different conditions.

11. Partial molar properties.

12. Fugacity and chemical potential.

13. Phase equilibria of single component systems.

14. Vapor pressures and related properties (experimental and estimation methods).

http://www.vscht.cz/fch/cz/pomucky/sbcht/StavoveChovani_SbirkaPrikladu.pdf

http://www.vscht.cz/fch/cz/pomucky/sbcht/StavoveChovani_SbirkaPrikladu.pdf