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Molar mass distributions of polymers, polymer conformation, thermodynamics of polymer solutions and blends, theoretical basics of methods used in determination of polymer molar mass and polymer-solvent interactions, polymerization kinetics. Last update: Rossner Christian (14.08.2025)
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In order to complete the subject the student has to pass a written examination test with a result better than 50%. Last update: Rossner Christian (09.09.2024)
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D: M. Chanda: Introduction to Polymer Science and Chemistry, CRC Press 2006; ISBN 978-0-8493-7384-8 D: L.H. Sperling: Introduction to Physical Polymer Science, John Wiley & Sons Inc. 2006; ISBN 978-0-471-70606-9 D: D: S. Koltzenburg, M. Maskos, O. Nuyken: Polymer Chemistry, Springer, 2017; ISBN 978-3-662-49277-2
Last update: Brožek Jiří (27.06.2024)
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1. Molar mass averages, distribution of molar mass. 2. Molar mass distribution functions, the most probable and other distribution functions. 3. Polymer chain dimensions, end-to-end distance, radius of gyration. 4. Thermodynamics of polymer solutions, entropy, enthalpy and Gibbs energy of mixing. 5. Solubility parameters, phase diagram polymer-solvent and polymer-solvent-nonsolvent. 6. Principles of Scattering and static light scattering from polymer solutions. 7. Small-angle X-ray scattering, small-angle neutron scattering, dynamic light scattering. 8. Viscosity of polymer solutions, Einsten equation, determination of limiting viscosity number. 9. Mark-Houwink equation, viscometry methods. 10. Colligative properties in determination of molar mass. 11. Size exclusion chromatography, calibration, concentration and molar mass detectors. 12. Polymerization kinetics. Last update: Rossner Christian (14.08.2025)
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| Teaching methods | ||||
| Activity | Credits | Hours | ||
| Účast na přednáškách | 1.5 | 42 | ||
| Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 2 | 56 | ||
| Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
| 5 / 5 | 140 / 140 | |||