SubjectsSubjects(version: 954)
Course, academic year 2023/2024
  
Spectroscopic Characterization of Heterogeneous Catalysts - AP105008
Title: Spectroscopic Characterization of Heterogeneous Catalysts
Guaranteed by: Department of Inorganic Technology (105)
Faculty: Faculty of Chemical Technology
Actual: from 2019
Semester: both
Points: 0
E-Credits: 0
Examination process:
Hours per week, examination: 3/0, other [HT]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
State of the course: taught
Language: English
Teaching methods: full-time
Teaching methods: full-time
Level:  
Note: course is intended for doctoral students only
can be fulfilled in the future
you can enroll for the course in winter and in summer semester
Guarantor: Sobalík Zdeněk doc. Ing. CSc.
Interchangeability : P105008
Annotation -
The aim of the course is to make students acquainted with modern approaches to the characterization of heterogeneous catalysts by spectroscopic methods, with emphasis on experiments under conditions in situ or Operands. In addition to repeating of method principle and the process of the catalysts preparation, the main procedures of structural and surface analysis of catalysts in the process of their preparation, using and deactivation are discussed. Lectures are supplemented with examples of solutions of structural problems and dealing with the relationship between the structure and activity of heterogeneous catalysts.
Last update: Pátková Vlasta (19.11.2018)
Aim of the course -

Students will be able to

  • analyze the structure and surface properties of heterogeneous catalysts
  • independently evaluate and discuss the obtained data
  • choose the appropriate combination of methods for the characterization of any catalyst
Last update: Pátková Vlasta (19.11.2018)
Literature -

R: B.A. Averill, J.A. Moulijn, R.A. van Santen, P.W.N.M. van Leeuwen: Catalysis: An Integrated Approach (Studies in Surface Science and Catalysis, Vol. 123) (Elsevier)

R: J. W. Niemantsverdriet: Spectroscopy in Catalysis (Wiley)

A: M. Che and J.C. Védrine: Characterization of Solid Materials and Heterogeneous Catalysts: From Structure to Surface Reactivity (Wiley)

Last update: Pátková Vlasta (19.11.2018)
Learning resources -

www.journals.elsevier.com

Last update: Pátková Vlasta (19.11.2018)
Teaching methods -

lectures, demonstration of the studied techniques

Last update: Pátková Vlasta (19.11.2018)
Requirements to the exam -

none

Last update: Pátková Vlasta (19.11.2018)
Syllabus -

The subject is focused on the following topics:

1. Preparation of catalyst and its characterization, overview of available methods

2. Electron spectroscopy (XPS, UPS, AES, EELS)

3. Ion spectroscopy (SIMS, SNMS, LEIS)

4. Vibration spectroscopy (infrared, Raman)

5. Temperature-programmed techniques(TPR, TPO, TPD)

6. Difraction techniques (XRD, EXAFS) and microscopy (TEM, SEM, STEM, STM, AFM)

7. Demonstration of the most of the described techniques

Last update: Pátková Vlasta (19.11.2018)
Entry requirements -

none

Last update: Pátková Vlasta (19.11.2018)
Registration requirements -

none

Last update: Pátková Vlasta (19.11.2018)
Course completion requirements -

Processing and defense of seminary work. Oral exam.

Last update: Pátková Vlasta (19.11.2018)
 
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