SubjectsSubjects(version: 955)
Course, academic year 2019/2020
Engineering Thermodynamics - N105011
Title: Inženýrská termodynamika
Guaranteed by: Department of Inorganic Technology (105)
Faculty: Faculty of Chemical Technology
Actual: from 2019
Semester: winter
Points: winter s.:7
E-Credits: winter s.:7
Examination process: winter s.:
Hours per week, examination: winter s.:3/2, C+Ex [HT]
Capacity: unknown / unknown (unknown)
Min. number of students: unlimited
State of the course: cancelled
Language: Czech
Teaching methods: full-time
Teaching methods: full-time
Guarantor: Krýsa Josef prof. Dr. Ing.
Paidar Martin doc. Ing. Ph.D.
Interchangeability : S105011
Is interchangeable with: S105011, M105004
Examination dates   Schedule   
Annotation -
The module belongs among the basic subjects of the inorganic technology specialization. In the frame of this module students obtain the knowledge from the field of phase equilibria of condensed systems, chemical equilibria and electrochemistry. Emphasis is given to theoretical principles as well as to their connection with real processes in chemical industry.
Last update: Krýsa Josef (14.11.2012)
Aim of the course -

Students will be able to:

  • create phase diagrams of condensed systems for 2, 3 and 4 components
  • calculate the equilibrium composition for chemical reactions at given pressure and temperature
  • calculate equilibrium potencial of electrochemical system
  • determine electrochemical reaction rate of common electrochemical systems which are controlled by charge transport or mass transport
Last update: Paidar Martin (15.08.2013)
Literature -

R: M. Malinovský, I.Roušar a kol., Teoretické základy pochodů anorganické technologie, SNTL/ALFA, 1987

R: R. Mráz, J. Krýsa, Příklady z chemicko-inženýrské termodynamiky, skripta VŠCHT Praha, 1991

Last update: ROZ105 (02.07.2013)
Learning resources -

recommended literature

database of salts solubilities

database of thermodynamic properties of chemical substances

database of standard electrode potencials

Last update: ROZ105 (14.08.2013)
Requirements to the exam -

For successful course pass:

test from each part must be at least 50% (1 possible repetition for each test)

exam consists from written and oral part

Last update: Paidar Martin (15.08.2013)
Syllabus -

1. Phase equilibrium in two component systems.

2. Phase equilibrium in three component systems. Graphical representation.

3. Phase equilibrium in four component systems. Graphical representation.

4. Cyclic crystallization between two temperatures.

5. Basic thermodynamic principles, reaction enthalpy, entropy, Gibbs energy.

6. State behavior of gases, relations for behavior of gaseous and liquid mixtures.

7. Conditions for equilibrium in systems with chemical reaction.

8. Equilibrium composition for reactions taking place in liquid and gaseous phase. Heterogeneous systems (gas - solid phase).

9. Simultaneous chemical equilibrium.

10. Adiabatic balance for chemical reaction. Limitation by equilibrium.

11. Charge transport in electrolytes. Basic laws in electrochemistry.

12. Electrode kinetics, activation overpotential.

13. Concentration overpotential. Limiting current density, Mixed electrode potential.

14. Shapes of polarization curves, hydrogen overpotential, oxygen overpotential, polarization curve of Fe in H2S04.

Last update: ROZ105 (15.08.2013)
Entry requirements -

following courses passed:

Physical chemistry

Chemical engineering

Last update: Paidar Martin (06.10.2009)
Registration requirements -

Physical Chemistry I

Chemical Engineering I

Last update: ROZ105 (02.07.2013)
Teaching methods
Activity Credits Hours
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 2.1 60
Příprava na zkoušku a její absolvování 2.9 82
5 / 7 142 / 196
Coursework assessment
Form Significance
Regular attendance 10
Examination test 30
Continuous assessment of study performance and course -credit tests 30
Oral examination 30