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Last update: ROZ105 (20.01.2015)
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Last update: ROZ105 (20.01.2015)
Students will be able to: • create phase diagrams of condensed systems for 2, 3 and 4 components • calculate the equilibrium composition for chemical reactions at given pressure and temperature • calculate equilibrium potencial of electrochemical system • determine electrochemical reaction rate of common electrochemical systems which are controlled by charge transport or mass transport |
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Last update: Krýsa Josef prof. Dr. Ing. (23.01.2015)
1. Physical Chemistry (Second Edition), Robert G. Mortimer, ISBN: 978-0-12-508345-4 2. Ullmann's Encyclopedia of Industrial Chemistry.John Wiley and Sons, Inc. Online ISBN: 9783527306732 3. Chemical Thermodynamics, Leo Lue, ISBN: 978-87-7681-497-7 http://bookboon.com/cs/chemical-thermodynamics-ebook |
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Last update: ROZ105 (20.01.2015)
recommended literature database of salts solubilities database of thermodynamic properties of chemical substances database of standard electrode potencials |
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Last update: ROZ105 (20.01.2015)
1. Phase equilibrium in two component systems. 2. Phase equilibrium in three component systems. Graphical representation. 3. Phase equilibrium in four component systems. Graphical representation. 4. Cyclic crystallization between two temperatures. 5. Basic thermodynamic principles, reaction enthalpy, entropy, Gibbs energy. 6. State behavior of gases, relations for behavior of gaseous and liquid mixtures. 7. Conditions for equilibrium in systems with chemical reaction. 8. Equilibrium composition for reactions taking place in liquid and gaseous phase. Heterogeneous systems (gas - solid phase). 9. Simultaneous chemical equilibrium. 10. Adiabatic balance for chemical reaction. Limitation by equilibrium. 11. Charge transport in electrolytes. Basic laws in electrochemistry. 12. Electrode kinetics, activation overpotential. 13. Concentration overpotential. Limiting current density, Mixed electrode potential. 14. Shapes of polarization curves, hydrogen overpotential, oxygen overpotential, polarization curve of Fe in H2S04. |
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Last update: ROZ105 (20.01.2015)
Physical Chemistry Chemical Engineering |
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Last update: ROZ105 (20.01.2015)
For successful course pass: test from each part must be at least 50% (1 possible repetition for each test) exam consists from written and oral part |
Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 2.1 | 60 | ||
Příprava na zkoušku a její absolvování | 2.4 | 66 | ||
Účast na seminářích | 1 | 28 | ||
7 / 7 | 196 / 196 |