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The subject deals with polymer molecular and supramolecular structure, network formation, free volume concept, glass transition, crystallization, linear and rubber elasticity, viscoelasticity, melt flow properties, yielding and fracture, miscibility and swelling of polymers, electrical properties, transport properties. Fundamental knowledge of differential and integral calculi, combinatorics, thermodynamics and chemical structure of basic polymers are required. Exemplars and tasks for homework will be given at lectures. The exam consists of written (imposition with similar tasks) and oral part.
Last update: Fialová Jana (15.08.2013)
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R: Meissner B., Zilvar V.: Fyzika polymerů, SNTL Praha 1987 A: Strobl G.: The Physics of Polymers, Springer, Berlin Heidelberg 2007, ISBN: 978-3-540-25278-8 A: Mills N.J.: Plastics. Microstructure and Engineering Applications. Third edition. Elsevier, Oxford, 2005. ISBN: 978-0-7506-5148-6 A: Ward I.M., Hadley D.W.: An Introduction to the Mechanical Properties of Solid Polymers. Xiley, Chichester 1998. ISBN: 0-471-93887-4 A: Mark J.E., Burak Erman B., Eirich F.R.: Science and Technology of Rubber. Third edition. Elsevier, New York, 2005. ISBN: 0-12-464789-3 Last update: TAJ112 (14.08.2013)
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1. Molecular structure, conformation, intermolecular forces, morphology of polymers. 2. Molar mass distribution, its effect on polymer properties. 3. Network formation, crosslinking theory, network structure. 4. Glass transition and free volume concept. 5. Thermodynamics and kinetics of crystallization. 6. Theory of rubber elasticity, its applications. 7. Viscoelasticity, models, Boltzmann superposition principle. 8. Transitions and polymer structure. Theorem of corresponding states. 9. Polymer melt flow properties - effects of shear rate, molar mass, temperature. 10. Mechanical properties. Introduction to fracture mechanics. 11. Miscibility and solubility of polymers. Phase separation. 12. Effects of anisotropy (orientation) on polymer properties. Polymer composites. 13. Electrical conductivity. Dielectric properties. 14. Diffusion of gases in polymer membranes. Heat capacity. Last update: Fialová Jana (15.08.2013)
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Meissner B., Zilvar V.: Fyzika polymerů, SNTL Praha 1987 (http://eso.vscht.cz) Kolektiv: Sbírka příkladů z makromolekulární chemie (http://eso.vscht.cz) Texts supporting lectures available at the teacher. Last update: TAJ112 (14.08.2013)
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Students will be able to: understand and describe fundamental physical properties of polymer materials. select suitable polymer material(s) for the product/application. Last update: TAJ112 (28.11.2013)
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Jsou vyžadovány základní znalosti diferenciálního a integrálního počtu, základů kombinatoriky a termodynamiky, názvosloví makromolekulární chemie, chemická struktura hlavních polymerů. Last update: Kuta Antonín (15.11.2012)
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Physical Chemistry, Macromolecular Chemistry Last update: TAJ112 (14.08.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1 | 28 | ||
Příprava na zkoušku a její absolvování | 1.5 | 42 | ||
Účast na seminářích | 0.5 | 14 | ||
4 / 4 | 112 / 112 |
Coursework assessment | |
Form | Significance |
Regular attendance | 20 |
Continuous assessment of study performance and course -credit tests | 40 |
Oral examination | 40 |