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This course extends the basic course Physical Chemistry I with focus on biological sciences. Covered are general laws governing behavior of systems from the molecular point of view as well as applications in biochemistry and colloidal chemistry. Alternatives are Physical Chemistry II (N403014) and Physical Chemistry of Microcosmos N403041).
Last update: Kolafa Jiří (07.11.2012)
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STUDENT WILL BE ABLE TO: Solve moderately complex equilibria in electrolyte solutions Solve moderately complex tasks including chemical kinetics of enzymatic reactions Transform the idea of forces between the molecules in systems as membranes, charged surfaces, or dispersions into consequences Last update: Kolafa Jiří (08.02.2018)
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BASIC: Novák J. a kol., Fyzikální chemie - bakalářský a magisterský kurz, VŠCHT, Praha 2008, 9788070806753 J. Kolafa: Vybrané kapitoly z fyzikální chemie (http://old.vscht.cz/fch/cz/pomucky/kolafa/fkch.pdf)
EXTENDED: Bartovská L., Šišková M., Fyzikální chemie povrchů a koloidních soustav, VŠCHT Praha, 2010, 9788070807453 Israelichvili J.: Intermolecular & Surface Forces, Academic Press (2006), 9780123919274. Atkins P. W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 Wright M. R.: An Introduction to Aqueous Electrolyte Solutions, Wiley (2007), 9780470842935. Last update: Kolafa Jiří (08.02.2018)
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See http://old.vscht.cz/fch/cz/pomucky/kolafa/FCHaKoloidInfo.pdf Last update: Kolafa Jiří (08.02.2018)
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1. Chemical kinetics: Simple and simultaneous reactions, reaction mechanisms, catalysis, enzyme kinetics. 2. Equilibrium thermodynamics: Gibbs and Helmholtz functions, activity, chemical potential. 3. Chemical equilibrium/methods: The direction of chemical reaction, simultaneous reactions, minimization of the Gibbs energy, van't Hoff equation. 4. Chemical equilibrium/applications: pH, weak acids and bases and their salts, buffers, slightly soluble salts. 5. Introduction to statistical thermodynamics: pressure of ideal gas and the interpretation of temperature, Boltzmann probability, entropy. 6. Electrostatic phenomena in ionic solutions: Debye-Hückel theory, electrical double layer, zeta potential. 7. Electrochemistry: Galvanic cells, Nernst equation, Gibbs-Donnan effect. 8. Thermodynamics of mixtures: Colligative properties (cryoscopy, ebullioscopy, osmosis). 9. Nonequilibrium thermodynamics: Transport properties, Fick laws, diffusivity, electrical conductivity. 10. Interfaces: Surface and interface tension, curved interfaces, wetting. 11. Adsorption: Surface excess and Gibbs adsorption isotherm. Adsorption isotherms and models (Freundlich, Langmuir, BET). 12. Dispersion systems/classification: Colloid, sol, gel, foam, emulsion, aerosol; solutions of macromolecules; micelles, surface films. 13. Dispersion systems/phenomena: Forces between colloidal particles. Sedimentation, electrokinetic phenomena, rheology, optical properties. Stability of colloidal systems. 14. Water: Structure and anomalies of water, hydrophobic effect. Last update: Kolafa Jiří (08.02.2018)
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http://old.vscht.cz/fch/cz/pomcky/kolafa/N403016.html (see also http://old.vscht.cz/fch/en/tools/kolafa/S403016.html in English) Various materials on Physical Chemistry in English: https://ufch.vscht.cz/studies Co je co v povrchové a koloidní chemii - výkladový slovník, L. Bartovská L., M. Šišková (http://vydavatelstvi.vscht.cz/knihy/uid_es-001/) Last update: Kolafa Jiří (08.02.2018)
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Physical Chemistry I Last update: Kolafa Jiří (21.08.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 2 | 56 | ||
Příprava na zkoušku a její absolvování | 2.5 | 70 | ||
Účast na seminářích | 1 | 28 | ||
7 / 7 | 196 / 196 |
Coursework assessment | |
Form | Significance |
Examination test | 40 |
Continuous assessment of study performance and course -credit tests | 40 |