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The course deals with selected chapters of physical chemistry on advanced level. Knowledge acquired in the basic course Physical Chemistry I is extended to real-behaving systems. Subjects covered involve state behavior of matter, thermodynamics of fluids, phase and chemical equilibria, properties of electrolyte-containing systems, chemical kinetics, and basic concepts of surface chemistry.
Last update: Dohnal Vladimír (16.08.2013)
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A: A. Malijevský, et. al: Physical chemistry in brief. Institute of Chemical Technology, Prague, 2005. (www.vscht.cz/fch/en/tools/breviary.html) A: Atkins P.W., de Paula J., Physical Chemistry, Oxford University Press, 2010, 9780199543373 A: Atkins P.W., de Paula J., Fyzikální chemie, Czech Edition, VŠCHT Praha, 2013, 9788070808306 Last update: KNOBLOCL (17.12.2015)
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Combination of lectures and seminar meetings. Last update: Dohnal Vladimír (16.08.2013)
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1. Molecular approach to physical chemistry. 2. Equations of state for real fluids, theorem of corresponding states. 3. Energetics of chemical reactions, enthalpy balance. 4. Implications of I. and II. Laws of thermodynamics, temperature and presseure dependences of state functions. 5. Thermodynamics of irreversible processes, heat engines, liquefacation of gases. 6. Thermodynamics of solutions, fugacity, activity. 7. Phase equilibia in real systems. 8. Spontaneous chemical change and Gibbs energy, chemical equilibrium in systems of various types. 9. Theory of electrolytic dissociation, equilibria in electrolyte solutions. 10.Difusion, migration of ions in electric field, conductivity, Kohlrausch law. 11.Reversible galvanic cells, types of electrodes, galvanic cells as power sources. 12.Kinetics of simultaneous reactions, kinetics and chemical equilibrium. 13.Reaction mechanisms; photochemical,radical, and catalyzed reactions. 14.Introduction to surface chemistry. Last update: Dohnal Vladimír (16.08.2013)
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http://www.vscht.cz/fch/en/tools/index.html http://www.vscht.cz/fch/cz/pomucky/index.html (in Czech) Last update: Dohnal Vladimír (16.08.2013)
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Students will be able to:
Last update: Dohnal Vladimír (16.08.2013)
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Necessary prerequisites for the enrollment are courses N413003 (Mathematics II) and N403011 (Physical Chemistry I). Knowledge of mathematics and physics on the advanced level is needed and expected. Last update: Dohnal Vladimír (16.08.2013)
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Mathematics II, Physical Chemistry I Last update: Dohnal Vladimír (16.08.2013)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Konzultace s vyučujícími | 0.5 | 13 | ||
Účast na přednáškách | 1.5 | 42 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1.5 | 42 | ||
Příprava na zkoušku a její absolvování | 2.5 | 70 | ||
Účast na seminářích | 1 | 28 | ||
7 / 7 | 195 / 196 |
Coursework assessment | |
Form | Significance |
Examination test | 25 |
Continuous assessment of study performance and course -credit tests | 25 |
Oral examination | 50 |