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The course covers the basic branches of physical chemistry: fundamentals of thermodynamics, state behavior, phase equilibria, chemical equilibria, selected behavior of systems containing electrolytes, the issue described the rate of chemical reactions and sipmle description of colloidal systems.
Last update: Řehák Karel (08.02.2018)
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Acquiring credit (meeting the minimum requirements of the computational part) The exam test Last update: Řehák Karel (02.03.2018)
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R: Novák J. a kol.,Fyzikální chemie - bakalářský kurz,VŠCHT Praha,2005,9788070806753 R: Malijevský a kol.,Breviář z fyzikální chemie,VŠCHT Praha,2000,9788070802987 A: Lidmila Bartovská, Marie Šišková: Fyzikální chemie povrchů a koloidních soustav,VŠCHT Praha,2010,9788070807453 Last update: Řehák Karel (08.02.2018)
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1. Basic concepts of thermodynamics system, thermodynamic process, thermodynamics variables. Equation of state of an ideal gas. Real gas and description of its behavior. 2. First law of thermodynamics, internal energy, heat, work, and their calculation. 3. Enthalpy, standard enthalpy of reaction, standard enthalpy of formation, Hess's and Kirchhoff's laws. 4. Second law of thermodynamics, entropy. Entropy calculation for proceses. 5. Helmholtz and Gibbs energy of their significance. Third law of thermodynamics. Chemical potential, activity, standard states. 6. Phase equilibria in one-component systems, Clapeyron equation. 7. Gibbs phase rule, vapor-liquid equilibrium in ideal systems, phase diagrams. 8. Solubility of gases in liquids, equilibrium in condensed systems. 9. Chemical equilibrium. Balance of a chemical reaction. Equilibrium constant. Ion balance. 10. Influencing the balance of chemical reactions. 11. Faraday's laws, galvanic cells, Nernst equation. 12. Basic concepts of chemical kinetics, simple reaction 13. Integration of kinetic equations, the dependence on temperature, catalysis 14. Colloidal chemistry, classification of colloidal systems, interfacial tension and its consequences Last update: Řehák Karel (08.02.2018)
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Basic information and learning resources: See the E-learning
Other literature and learning applications: https://ufch.vscht.cz/studium/literatura https://ufch.vscht.cz/studium/elektronicke_pomucky
Last update: Řehák Karel (08.02.2018)
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Students will be able to: understand basic concepts and laws of thermodynamics explain and calculate simple phase and chemical equilibrium describe and calculate basic problems of chemical kinetics basic concepts for other areas of physical chemistry: electrochemistry, colloidal and surface chemistry Last update: Řehák Karel (08.02.2018)
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Mathematics A Last update: Řehák Karel (08.02.2018)
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none Last update: Řehák Karel (08.02.2018)
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Teaching methods | ||||
Activity | Credits | Hours | ||
Účast na přednáškách | 1 | 28 | ||
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi | 1 | 28 | ||
Příprava na zkoušku a její absolvování | 2.5 | 70 | ||
Účast na seminářích | 0.5 | 14 | ||
5 / 5 | 140 / 140 |