SubjectsSubjects(version: 865)
Course, academic year 2019/2020
  
Basic Principles of Physical Chemistry - N403032
Title: Základy fyzikální chemie
Guaranteed by: Department of Physical Chemistry (403)
Actual: from 2017 to 2019
Semester: both
Points: 5
E-Credits: 5
Examination process:
Hours per week, examination: 2/1 C+Ex [hours/week]
Capacity: winter:unknown / unknown (unknown)
summer:unknown / unknown (unknown)
Min. number of students: unlimited
Language: Czech
Teaching methods: full-time
Level:  
For type:  
Additional information: http://www.vscht.cz/fch/cz/vitejte/index.html
Note: course can be enrolled in outside the study plan
enabled for web enrollment
you can enroll for the course in winter and in summer semester
Guarantor: Řehák Karel doc. Ing. CSc.
Class: Předměty pro fyzikální chemii
Incompatibility : N403011, N403014
Z//Is interchangeable with: N403011A, B403003, N403011
This subject contains the following additional online materials
Annotation -
Last update: Labík Stanislav prof. Ing. CSc. (25.06.2013)
The course covers the basic branches of physical chemistry: fundamentals of thermodynamics​​, state behavior, phase equilibria, chemical equilibria, selected behavior of systems containing electrolytes, the issue described the rate of chemical reactions and sipmle description of colloidal systems.
Aim of the course -
Last update: Labík Stanislav prof. Ing. CSc. (25.06.2013)

Students will be able to:

understand basic concepts and laws of thermodynamics

explain and calculate simple phase and chemical equilibrium

describe and calculate basic problems of chemical kinetics

basic concepts for other areas of physical chemistry: electrochemistry, colloidal and surface chemistry

Literature -
Last update: TAJ403 (12.08.2013)

R: Novák J. a kol.,Fyzikální chemie - bakalářský kurz,VŠCHT Praha,2005,9788070806753

R: Malijevský a kol.,Breviář z fyzikální chemie,VŠCHT Praha,2000,9788070802987

A: Lidmila Bartovská, Marie Šišková: Fyzikální chemie povrchů a koloidních soustav,VŠCHT Praha,2010,9788070807453

Learning resources -
Last update: Labík Stanislav prof. Ing. CSc. (25.06.2013)

Lecture presentations:

http://www.vscht.cz/fch/cz/pomucky/labik/index.html

Other materials:

http://www.vscht.cz/fch/cz/pomucky/index.html

Syllabus -
Last update: Labík Stanislav prof. Ing. CSc. (25.06.2013)

1. Basic concepts of thermodynamics system, thermodynamic process, thermodynamics variables. Equation of state of an ideal gas. Real gas and description of its behavior.

2. First law of thermodynamics, internal energy, heat, work, and their calculation.

3. Enthalpy, standard enthalpy of reaction, standard enthalpy of formation, Hess's and Kirchhoff's laws.

4. Second law of thermodynamics, entropy. Entropy calculation for proceses.

5. Helmholtz and Gibbs energy of their significance. Third law of thermodynamics. Chemical potential, activity, standard states.

6. Phase equilibria in one-component systems, Clapeyron equation.

7. Gibbs phase rule, vapor-liquid equilibrium in ideal systems, phase diagrams.

8. Solubility of gases in liquids, equilibrium in condensed systems.

9. Chemical equilibrium. Balance of a chemical reaction. Equilibrium constant. Ion balance.

10. Influencing the balance of chemical reactions.

11. Faraday's laws, galvanic cells, Nernst equation.

12. Basic concepts of chemical kinetics, simple reaction

13. Integration of kinetic equations, the dependence on temperature, catalysis

14. Colloidal chemistry, classification of colloidal systems, interfacial tension and its consequences

Entry requirements -
Last update: TAJ403 (27.09.2013)

Mathematics I

Registration requirements -
Last update: TAJ403 (27.09.2013)

none

Teaching methods
Activity Credits Hours
Konzultace s vyučujícími 0,5 14
Účast na přednáškách 1 28
Příprava na přednášky, semináře, laboratoře, exkurzi nebo praxi 1,5 42
Příprava na zkoušku a její absolvování 1,5 42
Účast na seminářích 0,5 14
5 / 5 140 / 140
Coursework assessment
Form Significance
Examination test 50
Continuous assessment of study performance and course -credit tests 50

 
VŠCHT Praha